The Late Triassic Carnian Pluvial Episode (CPE) witnessed enormous climate change closely associated with volcanic activity. However, the coupling relationship between volcanic activity and climate change, which may be linked to chemical weathering, has not yet been fully uncovered. We used lithium contents and isotopes of volcanic ash (VA)–bearing lacustrine shale to constrain their deposition pathways and response to climate changes, i.e., weathering intensity, during the Late Triassic era. Elevated δ ⁷ Li (i.e., >2.5‰) and low Li contents (i.e., 135 microgram per gram), alongside relatively low δ ⁷ Li (i.e., <0‰), likely implying waterborne VA dominated by intensified weathering under a super humidity climate. Hence, this study provides evidence for the differential VA-rich shale deposition model related to chemical weathering states synchronous with climate changes during the CPE period.

During diagenesis, the transformation of unconsolidated sediments into a sandstone is usually accompanied by compaction, water expulsion, cementation and dissolution, which fundamentally control the extent, connectivity and complexity of the pore structure in sandstone. As the pore structure is intimately related to fluid flow in porous media, it is of great importance to characterize the pore structure of a hydrocarbon-bearing sandstone in a comprehensive way. Although conventional petrophysical methods such as mercury injection porosimetry, low-pressure nitrogen or carbon dioxide adsorption are widely used to characterize the pore structure of rocks, these evaluations are based on idealized pore geometry assumptions, and the results lack direct information on the pore geometry, connectivity and tortuosity of pore channels. In view of the problems, X-ray micro-CT was combined with ImageJ software (version 1.8.0) to quantitatively characterize the pore structure of Berea Sandstone. Based on its powerful image processing function, a series of treatments such as contrast enhancement, noise reduction and threshold segmentation, were first carried out on the micro-CT images of the sandstone via ImageJ. Pores with sizes down to 2.25 μm were accurately identified. Geometric parameters such as pore area, perimeter and circularity could thus be extracted from the segmented pores. According to our evaluations, pores identified in this study are mostly in the range of 30–180 μm and can be classified into irregular, high-circularity and slit-shaped pores. An irregular pore is the most abundant type, with an area fraction of 72.74%. The average porosity obtained in the image analysis was 19.10%, which is fairly close to the experimental result determined by a helium pycnometer on the same sample. According to the functional relationship between tortuosity and permeability, the tortuosity values of the pore network were estimated to be in the range of 4–6 to match the laboratory permeability data.

Resolving the role of galactic processes in Solar System/Earth events necessitates a robust temporal model. However, astrophysical theory diverges with models varying from long-lasting spiral density waves with uniform pattern speeds and arm structures to others with fleeting and unpredictable features. Here, we address those issues with (1) an analysis of patterns of impact periodicity over periods of 10 to 250 million years (Myr) using circular statistics and (2), an independent logarithmic spiral arm model fitted to arm tangents of 870 micron dust. Comparison of the impact periodicity results with the best-fit spiral arm model suggests a galactic period of 660 Myr, i.e. 165 Myr to pass from one arm to the next in a four spiral arm model, with the most recent arm passage around 52 million years ago (Ma). The oldest impact ages imply that the emerging galactic chronology model is robust for at least the last 2 Gyr. The arm-passing time is consistent with spectral analyses of zircons across 3 Gyrs. Overall, the model provides a temporal framework against which to test hypotheses of galactic mechanisms for global events such as mass extinctions and superchrons.