Due to serious global warming and environmental issues, the demand for clean and sustainable energy storage devices is significantly increased. Often accompanied by rapid growth of portable electronic vehicles and devices, massive electromagnetic wave pollution becomes unavoidable. To mitigate the above two issues, this mini-review summaries preparation methods and recent developments of MXene/polyaniline-based composites for their applications in electrochemical devices and electromagnetic interference shielding. Based on excellent synergistic effects between single compounds and designed hierarchical structures, MXene/polyaniline-based composites usually exhibit enhanced physical and chemical properties, showing great potentials in sustainable electrochemical properties and electromagnetic wave protections for human health as well as normal operation of precise electronic devices.
A methoxy-decorated novel metal–organic framework (MOF), Cu2(DTPD) (ZJU-12, H4DTPD = 5,5′-(2,6-dimethoxynaphthalene-1,5-diyl)diisophthalic acid) with optimized pore space and open metal sites, was solvothermally synthesized and structurally characterized. The activated ZJU-12a displays a moderately high BET (Brunauer–Emmett–Teller) surface area of 2316 m2 g−1. Due to the pore size of the crystal being consistent with the molecular size and kinetic diameters of C2H2 and CO2, ZJU-12a exhibits a high C2H2 storage capacity of 244 cm3 g−1 and CO2 capture capacity of 134 cm3 g−1 at room temperature.
9 September 2020 in Zeitschrift für anorganische und allgemeine Chemie