Monitoring of various naturally present substances or physical properties of the water, commonly called environmental tracers, can provide valuable insight in characteristics of groundwater flow systems and intrinsic processes. Analysis of individual tracer data most often gives an ambiguous interpretation, but employment of multiple diverse tracers can greatly increase interpretation reliability. We monitored multiple natural tracers including spring water electrical conductivity, temperature, loads of major anions and cations, stable isotopes of water, and total organic carbon together with discharge dynamics on Krbavica springs located in the Croatian part of Dinaric Karst region. We also monitored dissolved oxygen concentration as an indicator of “excess air” dynamics in the spring water, which is a very rarely recognized and not properly understood phenomenon in the karst groundwater studies. Analysis of the monitoring data revealed main characteristics of the karst system, among which following can be emphasized: (1) oxygen concentration together with conductivity and temperature (parameters monitored with high temporal resolution) were strongly related to discharge dynamics, while seasonal patterns were absent; (2) supersaturation with oxygen confirmed presence of “excess air”, most pronounced in high water conditions following the hydrograph peaks, indicating prevalence of closed flow conditions within the system; (3) electrical conductivity showed “anomalous” gradual decrease during the hydrograph recessions, attributed both to CO2 dynamics and mobilization of water from tiny fissures during high recharge conditions; and (4) stable isotope measurements confirmed good mixing of water within the system with mean residence time of a few years. Simultaneous monitoring of diverse tracer dynamics enabled detailed characterization of the karst system without excessive ambiguity.
The paper deals with complex hydrological/hydrogeological behaviour in the Rječina karst spring and river basin located in the north-western part of the deep and developed Croatian Dinaric karst. The Rječina Spring is one of the major karst springs in Croatia, used for water supply of Rijeka City and its surrounding area. Beside the use of Rječina spring for water supply, the development of the Rijeka hydroelectric power plant (HEPP) also changed hydrological and hydrogeological regime of the whole catchment. In order to analyse the anthropogenic influences in the system, hydrological analysis of the Rječina river and spring discharge was done, as well as the analysis of the available data of groundwater measurements. The analysis showed that, due to the increase of water caption and decrease of precipitation, the average annual spring discharge decreased for approximately 25% in the 1980-2016 period. Detailed analysis of groundwater measurements indicated aquifer behaviour and the need for additional measurements and catchment delineation.Key words: hydrology, hydrogeology, karst, Rječina Spring, Rječina River, Dinaric karst.Analiza vodnih virov kraškega izvira in reke Rječina (Dinarski kras)Članek obravnava zapletene hidrološke/hidrogeološke razmere v zaledju kraškega izvira in reke Riečine v severozahodnem delu globokega in dobro razvitega hrvaškega Dinarskega krasa. Izvir Rječina je eden največjih kraških izvirov na Hrvaškem, zajet je za oskrbo s pitno vodo za mesto Reka in njeno okolico. Poleg rabe izvira Rječine za oskrbo z vodo je razlog za spremenjen hidrološki in hidrogeološki režim celotnega zaledja tudi gradnja hidroelektrarne Reka (HEPP). Za analizo antropogenih vplivov na sistem smo zato naredili hidrološko analizo pretokov reke in izvira Rječina pa tudi analizo razpoložljivih podatkov merjenja podzemne vode. Analiza je pokazala, da se je zaradi povečanja zajemanja vode in zmanjšanja količine padavin povprečen letni pretok izvira v obdobju 1980–2016 zmanjšal za približno 25 %. Podrobna analiza meritev podzemne vode je nakazala značilnosti delovanja vodonosnika ter pokazala potrebo po dodatnih meritvah in določitvi zaledja izvira.Ključne besede: hidrologija, hidrogeologija, kras, izvir Rječina, reka Rječina, Dinarski kras.
Karst aquifers provide critical water resources in the Mediterranean region, yet climate change threatens their sustainability. This study integrates stable isotope analysis (δ2H, δ18O), hydrochemistry, and hydrological time series to characterize precipitation–groundwater dynamics in the Mt. Učka karst system (Croatia). Precipitation samples collected across an altitudinal gradient of approximately 1400 m and groundwater from three major groundwater sources were analyzed over a 2.5-year period. Precipitation exhibits pronounced isotopic variability with d-excess values indicating mixed Atlantic–Mediterranean moisture sources. Groundwater is primarily recharged by precipitation from the cold part of the hydrological year. It exhibits substantial attenuation of isotopic signals, which indicates extensive mixing processes but prevents quantitative estimation of mean residence time. Groundwater is predominantly recharged from elevations above 900 m a.s.l., with one spring showing evidence of higher-elevation recharge. Analysis confirms the system’s dual porosity: a rapid, conduit-dominated response indicates high vulnerability to surface contamination, while a sustained, matrix-dominated response provides greater buffering capacity. These findings highlight the vulnerability of karst systems to projected reductions in autumn precipitation, the critical recharge season, and demonstrate the necessity of multi-tracer approaches for comprehensive aquifer characterization.
Lake Vrana on Cres Island (northern Adriatic Sea) is a rare hydrogeological system consisting of a large freshwater body located within a karst cryptodepression with its bottom below sea level and surface above it. This study investigates long-term hydroclimatological changes using daily records of lake water level (1978–2024), water temperature (1979–2024), precipitation, and air temperature (1981–2024). Linear regression, the Mann–Kendall trend test, Sen’s slope estimator, and day-to-day variability metrics were applied to quantify long-term trends and system responses. A multi-index approach was used to enable a robust assessment of drought dynamics in this unique karst system: the Standardized Precipitation Index (SPI), representing meteorological conditions based on precipitation; the Standardized Hydrological Index (SHI), reflecting hydrological response derived from lake levels; and the New Drought Index (NDI), integrating precipitation and temperature to account for evapotranspiration effects. Results indicate a statistically significant decline in lake water levels (−4.5 to −5.2 cm yr−1), while precipitation shows no significant trend. In contrast, both air and water temperatures exhibit a significant increase (~0.5 °C per decade) and are strongly correlated (R2 = 0.767). The lake demonstrates pronounced thermal inertia and delayed response to atmospheric forcing. Day-to-day analysis reveals increasing variability in water temperature and decreasing variability in air temperature, suggesting changes in system energy dynamics. Drought indices (SHI and NDI) show significant negative trends, whereas SPI does not, indicating that drought intensification is primarily driven by rising temperatures and enhanced evapotranspiration rather than precipitation deficits. These findings demonstrate that Lake Vrana acts as a sensitive integrator of climatic forcing.
U radu je provedena ocjena pogodnosti područja za izgradnju solarnih parkova primjenom višekriterijske analize, i to metode analitičkog hijerarhijskog procesa (AHP) u GIS okruženju. U prvoj fazi analize pogodnosti izuzeta su područja nepogodna za izgradnju solarnih parkova, dok su u drugoj fazi klasificirane razine pogodnosti preostalih područja primjenom AHP metode.