Monitoring of various naturally present substances or physical properties of the water, commonly called environmental tracers, can provide valuable insight in characteristics of groundwater flow systems and intrinsic processes. Analysis of individual tracer data most often gives an ambiguous interpretation, but employment of multiple diverse tracers can greatly increase interpretation reliability. We monitored multiple natural tracers including spring water electrical conductivity, temperature, loads of major anions and cations, stable isotopes of water, and total organic carbon together with discharge dynamics on Krbavica springs located in the Croatian part of Dinaric Karst region. We also monitored dissolved oxygen concentration as an indicator of “excess air” dynamics in the spring water, which is a very rarely recognized and not properly understood phenomenon in the karst groundwater studies. Analysis of the monitoring data revealed main characteristics of the karst system, among which following can be emphasized: (1) oxygen concentration together with conductivity and temperature (parameters monitored with high temporal resolution) were strongly related to discharge dynamics, while seasonal patterns were absent; (2) supersaturation with oxygen confirmed presence of “excess air”, most pronounced in high water conditions following the hydrograph peaks, indicating prevalence of closed flow conditions within the system; (3) electrical conductivity showed “anomalous” gradual decrease during the hydrograph recessions, attributed both to CO₂ dynamics and mobilization of water from tiny fissures during high recharge conditions; and (4) stable isotope measurements confirmed good mixing of water within the system with mean residence time of a few years. Simultaneous monitoring of diverse tracer dynamics enabled detailed characterization of the karst system without excessive ambiguity.

Crystalline rocks are generally characterized by negligible porosity and permeability in terms of groundwater exploitability. However, alteration processes can greatly increase their fracture permeability and induce formation of modest, but locally important aquifers. Therefore, subsurface characteristics of alteration zones are of major importance for hydrogeological evaluation of crystalline terrains. Alteration processes greatly affect rock total porosity and water content, causing contrasting electrical resistivity of rocks affected by varying degrees of weathering. This makes electrical resistivity tomography (ERT) a preferable geophysical method for the exploration of alteration zones in crystalline rocks. In our research, we used an integrated approach, combining the ERT method with monitoring of spring discharge and hydrochemistry to characterize metamorphic aquifers on slopes of the Medvednica Mountain (Croatia). Significant fracture flow aquifers are found to be formed in intensely fractured but not highly weathered rock masses (medium to high resistivity values), while highly weathered masses (low resistivity values) form local barriers for fracture flows. Subsurface structure of the alteration zone proved to be highly irregular, with sharp contacts between more and less weathered rocks. Decrease of permeability below the alteration zone keeps the water level near the surface and enables spring occurrence on the mountain slopes. Studied aquifers have relatively limited extent, resulting in typical capacity of major springs of a few l/s. More frequent but less productive springs are attributed to the draining of the shallow part of the alteration zone (mostly saprolite). Combination of the ERT method with spring monitoring proved to be very effective as a first and relatively inexpensive methodology for hydrogeological characterization of crystalline terrains, both in local and catchment scales.

This paper presents a hydrogeological map of the western part of the Drava Basin in northern Croatia. An area of approximately 660 km² is included in the hydrogeological map at a scale of 1:100,000. The map was made using ESRI ArcGIS 10 and ArcMap 10.2.1. This map describes the geometry of the Quaternary aquifer system and its hydrogeological characteristics as well as the distribution of groundwater flow. According to the values of the hydrogeological conductivity, the deposits are classified into a single hydrogeological unit. Approximately 400 boreholes and wells are identified within the map. Five 2D lithological cross-sections and five 3D hydrogeological cross-sections are displayed on the map. The distribution of the covering deposits thickness and the lithological composition of the upper part of the covering deposits are also displayed. According to its hydrogeological characteristics, the Quaternary aquifer system in the study area represents a strategic groundwater resource in Croatia.

Topusko is the second warmest natural thermal water spring area in Croatia, located at the southwest edge of the Pannonian Basin System. Due to favourable geothermal properties, these waters have been used for heating and health and recreational tourism since the 1980s. Thermal springs with temperatures up to 50 °C are the final part of an intermediate-scale hydrothermal system. However, systematic research on the Topusko spring area has not been conducted to lay the foundation for sustainable resource utilisation. Multidisciplinary research including the hydrogeochemical characterisation of naturally emerging thermal water, an electrical resistivity tomography (ERT) investigation conducted to reconstruct the subsurface geology, and hydrogeological parametrisation of the geothermal aquifer was carried out to refine the existing local conceptual model. The results show Ca-HCO₃ facies of Topusko thermal waters, which get heated in a Mesozoic carbonate aquifer. The water equilibrium temperature in the geothermal aquifer is estimated to be 78 °C based on the SiO₂-quartz geothermometer. The fault damage zone, which enables the upwelling of thermal water, was identified by ERT investigations. The transmissivity values of the aquifer derived from the results of step-drawdown tests range from 1.8 × 10⁻² to 2.3 × 10⁻² m²/s. Further multidisciplinary research is necessary to improve the existing conceptual model of the Topusko hydrothermal system.

Tracer testing is the only method in karst hydrogeology that can definitively determine whether a particular site belongs to a watershed of a particular karst spring. Therefore, it is an essential technique for delineating groundwater basins in karst areas. The availability of tracer test results is often limited due to the complicated and relatively expensive application of this approach, especially for large regional watersheds. The Croatian part of the Dinaric karst region extends for several hundred kilometers along the Adriatic coast and consists almost entirely of highly karstified carbonate rocks. The groundwater basins in these areas almost never match the surface morphology of the terrain. In practice, all available results of previous surveys are often used to define watersheds, regardless of the methodology and age of their implementation. This is also true for the earlier delineations of the Gacka River watershed, a regional karst basin in the Croatian Dinaric karst. However, tracer testing methods, especially the accuracy of tracer determination and monitoring, have improved significantly during this time. In order to assess the reliability of past tracing results in this significant karst basin, we reviewed reports of previous tracer tests. More recent tests, in particular the most recent multitracer injection test with continuous tracer detection on the major springs, produced high-quality data that allowed us to assess the reliability of the findings from prior research. A number of large karst springs with partially overlapping subcatchments feed the Gacka River. After discarding unreliable tracing data, we reevaluated the subcatchments of the main springs as well as the characteristics of the regional groundwater flow patterns throughout the basin, which is particularly important for water quality protection measures of the springs. The Gacka River basin is used as a case study to emphasize the importance of thoroughly assessing the reliability of previous tracing data before using them in regional analyses.