Polyurethane grouting materials are polymer materials formed through the reaction of polyisocyanates and polyols. They play important roles in underground engineering, tunnel construction, and mining due to their fast reaction rate, high bonding strength, and excellent impermeability. However, traditional polyurethane grouting materials have shortcomings such as high reaction heat release, high brittleness, and poor flame retardancy, which limit their applications in high-demand engineering projects. This paper systematically reviews the research progress on modified polyurethane grouting materials. Four major modification technologies are summarized: temperature reduction modification, flame retardant modification, mechanical enhancement, and environmental adaptability improvement. A multi-dimensional performance characterization system is established, covering slurry properties, solidified body performance, microstructure characteristics, thermal properties and flame retardancy, diffusion grouting performance, and environmental adaptability. The application effects of modified polyurethane grouting materials in grouting reinforcement, grouting water plugging, and grouting lifting are analyzed. Future development directions are projected. This review is particularly valuable for researchers and engineers working in tunneling, mining, geotechnical engineering, and infrastructure rehabilitation.

Acrylate is a popular polymer grouting material that has been widely used to control groundwater seepage. However, the vulnerability of acrylate slurry to dynamic water washout restricts its application in groundwater environments characterized by high flow velocity and water pressures. In this paper, lithium bentonite (Li-B) was used to modify the traditional magnesium acrylate (AC) grouting material. The influence of Li-B to AC ratios on the modified materials’ washout resistance was explored, and the modification mechanism was analyzed using X-ray diffraction (XRD), infrared spectroscopy (IR), and scanning electron microscopy (SEM). Finally, the anti-washout ability of the modified slurry was verified through engineering applications. Results revealed that LiB-AC grout had adjustable setting times (10.5 to 395.6 s), minimal bleeding (0.1%), higher viscosity (65 mPa·s) and expansibility (350%), stronger anti-water dispersibility (24 times that of pure AC slurry), higher mechanical strength (compressive strength is 0.386 MPa, tensile strength is 0.088 MPa), and better impermeability (2.23 × 10⁻⁸ m/s). The lithium bentonite was beneficial to the setting time, bleeding, viscosity, slurry retention rate, impermeability, and mechanical strength of the acrylate grout. However, it diminished the expansibility of the acrylate grout. At the optimal acrylate content (20%), the mechanical strength and impermeability of the LiB-AC grout were the highest. The better performance of LiB-AC grout was attributed to the formation of a more stable and dense interlaced spatial network structure after the modification by Li-B. The LiB-AC grout was used in the dynamic water grouting project of a metro shield tunnel segment and achieved better anti-washout performance than cement-water glass and pure AC slurry.