We report on the first exfoliation of MoS2 coaxial nanotubes. The single-layer flakes, as the result of exfoliation, represent the transition metal dichalcogenides' analogue of graphene. They show a very low degree of restacking in comparison with exfoliation of MoS2 plate-like crystals. MoS2 monolayers were investigated by means of electron and atomic force microscopies, showing their structure, and ultraviolet-visible spectrometry, revealing quantum confinement as the consequence of the nanoscale size in the z-direction.

ZnO nanopowders were produced using microwave processing of a precipitate and applied as a photoanode for photoelectrochemical water splitting. Two different surfactants, cetyltrimethylammonium bromide (CTAB) as the cationic and Pluronic F127 as the non-ionic one, were employed to in situ adjust the surface-to-bulk defect ratio in the ZnO crystal structure and further to modify the photo(electro)catalytic activity of the ZnO photoanode. The crystal structure, morphological, textural, optical and photo(electro)catalytic properties of ZnO particles were studied in detail to explain the profound effects of the surfactants on the photoanode activity. The ZnO/CTAB photoanode displayed the highest photocurrent density of 27 mA g⁻¹, compared to ZnO (10.4 mA g⁻¹) and ZnO/F127 photoanodes (20 mA g⁻¹) at 1.5 V vs. SCE in 0.1 M Na₂SO₄ under visible illumination of 90 mW cm⁻². A significant shift of the overpotential toward lower values was also observed when photoanodes were illuminated. The highest shift of the overpotential, from 1.296 to 0.248 V vs. SCE, was recorded when the ZnO/CTAB photanode was illuminated. The ZnO/CTAB photoanode provides efficient charge transfer across the electrode/electrolyte interface, with a longer lifetime of photogenerated electron–hole pairs and reduced possibility of charge recombination. The photoconversion efficiency was improved from 1.4% for ZnO and 0.9% for ZnO/F127 to 4.2% for ZnO/CTAB at 0.510 mV. A simple procedure for the synthesis of ZnO particles with improved photo(electro)catalytic properties was established and it was found that even a small amount of CTAB used during processing of ZnO increases the surface-to-bulk defect ratio. Optimization of the surface-to-bulk defect ratio in ZnO materials enables increase of the absorption capacity for visible light, rendering of the recombination rate of the photogenerated pair, as well as increase of both the photocurrent density and photoconversion efficiency.

Structural analogy with antibacterial peptides provides antibacterial property in newly developed HAp/Au/arginine nanocomposite. The material possesses: (i) high antibacterial activity, (ii) high cytocompatibility and (iii) good stability in physiological environment.

Potable water supply system in major countries still uses a large proportion of asbestos-cement (AC) pipes for fresh drinking water delivery. Generally, after installation and initial purging, the AC tubes are believed to self-passivate by calcite scale and bio-film, especially when conveying hard water. However, the overall performance of AC tubes after decades of operation is significantly reduced and is still mainly unknown. In the current research, we investigated the AC water supply tube after 56 years of operation with high-hardness conveyed water. Our results show that asbestos fibres are emitted from degraded AC pipes as a result of wall softening due to calcium leaching from hydrated cementitious materials, resulting in the loss of mechanical stability. Although the water pumped into the system is not considered aggressive, the seasonal variations of water temperature and chemistry results in an interplay of calcite scaling and Ca leaching, the latter being the dominating process. By comparing the experimental observations with the long-term chemistry reports of the water supplied through the pipes, a positive relationship was established between the temperature and quality of the conveyed water with the corrosion and the calcite scale formation, which are dictating the emission of the fibres into the drinking water. In addition to the health risks posed by asbestos, these processes have many adverse effects on drinking water supply, such as pipe malfunction and destruction resulting in water loss, reduction of hydraulic capacity, microbial proliferation, and water quality deterioration, a topic of interest for global water industries process.