The purpose of this review is to provide a critical evaluation of the nutritional and sensory properties of ancient wheats (spelt, emmer, einkorn, and kamut) and the methods used to analyze them. This paper provides a comprehensive overview of the main analytical methods applied to study the nutritional properties of ancient wheats. According to our findings, protein content was the most commonly studied macronutrient across all types of ancient wheat species. The article notes that einkorn bran showed the highest protein and ash content, which reveals the potential of ancient wheats to be more widely used in food products. Regarding the majority of amino acids in spelt wheat cultivars, the general trend in the data was rather consistent. This review also compares sensory evaluation methods for different wheat products made from ancient wheats, such as bread, pasta, cooked grains, porridge, snacks, and muffins. The various reported methods and panel sizes used prove that ancient wheat products have many potential sensory advantages. Overall, using ancient wheats in wheat products can enhance the nutritional benefits, increase diversity in the food systems, and may be more appealing to consumers looking for something different, thereby contributing to the development of more sustainable and locally based food systems.

Reduced graphene oxide (rGO/polycation/sulfur) composites are promising cathode materials for Li-S battery applications because homogeneously dispersed sulfur nano/micro clusters in suitable carbon hosts enable remarkable cycle life for Li-S battery cells. New, benign and economic synthesis methods based only on aqueous colloidal dispersions are demanded for achieving high dispersity grade of sulfur within the carbon host. Colloidal interactions leading to heteroaggregation between carbonaceous lamellae and polycation-modified sulphur nanoparticles at ambient conditions in water are foreseen to afford nanocomposite cathodes, which maintain excellent electrochemical performance. Hydrophilic sulfur nanoparticles (SNPs) were coated by low doses of polycation (PDDA) until reaching the isoelectric point (IEP), and in high dose to achieve charge reversal. Streaming potential titrations were performed to reveal appropriate mass ratios of PPDA, SNP and GO. Positively charged SNPs formed stable heteroaggregated structures with GO, and were employed to fabricate rGO/polycation/sulphur cathodes. Charge reversal characteristics of SNPs, polycation and GO were characterized quantitatively and mass ratios of PDDA to SNP beyond IEP were found to mediate attractive interactions leading to rapid heteroaggregation between SNPs and GO and also alleviate lithium polysulfide migration. The composite cathode showed an initial discharge capacity of 522 mAhg^-1 at 0.2C rate with an excellent capacity retention of 91.4 % and coulombic efficiency of 98.5% after 100 charge-discharge cycles.