Owing to its outstanding physical and mechanical properties, polycrystalline diamond (PCD) is ideal for cutting titanium alloys. However, the high temperature and stress caused by the interaction of tool surface and chip flow lead to different types of wear. This paper investigates the wear mechanisms of PCD tools in three different tribological regions: sticking zone, transition zone, and sliding zone, when machining titanium alloy Ti6Al4V. The tribological behavior of PCD tools in the wear processes were analyzed through both experiments and theoretical calculations. Analytical models of stresses and temperature distribution were developed and validated by turning experiments. PCD tools, consisting of diamond grains of different sizes: CTB002 (2 μm), CTB010 (10 μm), and CTM302 (2–30 μm), were used to cut Ti6Al4V at the normal cutting speed of 160 m/min and high cutting speed 240 m/min. It was found that adhesion, abrasion and diffusion dominated the wear process of PCD tools in different worn regions. Microscopic characters showed that the wear mechanisms were different in the three tribological regions, which was affected by the distribution of stresses and temperature. “Sticking” of workpiece material was obvious on the cutting edge, abrasion was severe in the transition zone, and adhesion was significant in the sliding zone. The shapes and morphological characters in different worn regions were affected by the stresses distribution and the types of PCD materials.

Flexible reactive poly(glycidyl methacrylate)-b-poly(propylene glycol)-b-poly(glycidyl methacrylate) (GPG) and nonreactive poly(ethylene glycol)-b-poly(propylene glycol)-b-poly(ethylene glycol) (EPE80) were utilized to toughen a trifunctional epoxy (diglycidyl 4, 5-epoxycyclohexane-1, 2-dicarboxylate, TDE-85). In comparison with the nonreactive EPE80 and reactive GPG92 with long reactive blocks (L_reactive), the incorporation of reactive GPG83 with short L_reactive improved the comprehensive mechanical properties of the epoxy. Upon an optimal GPG83 loading of 2.5 wt%, the tensile strength, elongation at break and critical strain energy release rate (G_1c) increased by ca. 31%, 45.9% and 130.8%, respectively, without sacrificing the modulus and thermal stability. Morphology characterization evidenced that micro-scale domains and nanosized vesical micelles coexisted in the nonreactive EPE80 toughened systems. However, homogeneous morphologies were formed in reactive GPG83 and GPG92 toughened systems. Fracture morphology analysis suggested that GPG can toughen epoxy thermosets by incorporating flexible PPG blocks into the epoxy network, thereby enabling an energy dissipation mechanism. The good balance between the mobility of flexible PPG and degree of cross-link density leads to the simultaneous toughening and reinforcing effect of GPG83 toward the trifunctional epoxy.

In this study, a novel finishing method, entitled clustered magnetorheological finish (CMRF), was proposed to improve surface finish of the silicon nitride ( ${\mathrm{Si}}_3{\mathrm{N}}_4$ ) balls with ultra fine precision. The effects of different polishing parameters including rotation speeds, eccentricities and the machining gaps on surface finish of ${\mathrm{Si}}_3{\mathrm{N}}_4$ balls were investigated by analyzing the roughness, sphericity and the micro morphology of the machined surface. The experimental results showed that the polishing parameters significantly influenced the surface finish. The best surface finish was obtained by using the polishing parameters: the machining gap of 0.8 mm, the eccentricity of 10 mm and the rotation ratio of 3/4. To further investigate the influence of the polishing parameters on the surface finish, an analytical model was also developed to analyze the kinematics of the ceramic ball during CMRF process. The resulting surface finish, as a function of different polishing parameters employed, was evaluated by analyzing the visualized finishing trace and the distribution of the contact points. The simulative results showed that the distribution and trace of the contact points changed with different polishing parameters, which was in accordance with the results of experiments.