Fe₂O₃/TiO₂ nanocomposites were fabricated via a facile impregnation/calcination technique employing different amounts iron (III) nitrate onto commercial TiO₂ (P25 Aeroxide). The as-prepared Fe₂O₃/TiO₂ nanocomposites were characterized by X-ray diffraction (XRD), Raman spectroscopy (RS), scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDXS), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller analysis (BET), electron impedance spectroscopy (EIS), photoluminescence spectroscopy (PL), and diffuse reflectance spectroscopy (DRS). As a result, 5% (w/w) Fe₂O₃/TiO₂ achieved the highest photocatalytic activity in the slurry system and was successfully immobilized on glass support. Photocatalytic activity under visible-light irradiation was assessed by treating pharmaceutical amoxicillin (AMX) in the presence and absence of additional oxidants: hydrogen peroxide (H₂O₂) and persulfate salts (PS). The influence of pH and PS concentration on AMX conversion rate was established by means of statistical planning and response surface modeling. Results revealed optimum conditions of [S₂O₈²⁻] = 1.873 mM and pH = 4.808; these were also utilized in presence of H₂O₂ instead of PS in long-term tests. The fastest AMX conversion possessing a zero-order rate constant of 1.51 × 10⁻⁷ M·min⁻¹ was achieved with the photocatalysis + PS system. The AMX conversion pathway was established, and the evolution/conversion of formed intermediates was correlated with the changes in toxicity toward Vibrio fischeri. Reactive oxygen species (ROS) scavenging was also utilized to investigate the AMX conversion mechanism, revealing the major contribution of photogenerated h⁺ in all processes.

In this work, the behaviour of photoanodes made of TiO₂, SnS₂ and TiO₂/SnS₂ was examined in the presence and absence of pharmaceuticals diclofenac (DCF), memantine hydrochloride (MEM) and salicylic acid (SA). The focus of the current research is on the following photoelectrochemical (PEC) characterisation methods: linear polarisation, electrochemical impedance spectroscopy (EIS), and open circuit potential (OCP) monitoring. Linear polarisation and EIS provided useful information about the interaction between the pharmaceuticals and the photocatalytic materials. The presence of the selected pharmaceuticals affects the OCP value, mainly due to the pH change. The results obtained by PEC characterisation were compared to the photocatalytic (PC) efficiency of pharmaceutical degradation. In addition to the photocurrent response, the linear voltammogram indicates the electrochemical oxidation of DCF and SA. Geometry optimizations using density functional theory (DFT) showed that the HOMO orbitals’ position of DCF and SA are above the position of the TiO₂ HOMO level and below the position of the SnS₂ HOMO level. Due to this, the characteristic current peak for DCF and SA was registered, but only for TiO₂ and TiO₂/SnS₂ photoanodes. The oxidation current peak was not registered for MEM, although h⁺ scavenging properties were noticed for TiO₂ in the presence of MEM. Apparently, this is an interplay between the protonated and non-protonated forms of MEM and the differences in their HOMO positions.

Sustainable hydrogen production is one of the main challenges today in the transition to a green and sustainable economy. Photocatalytic hydrogen production is one of the most promising technologies, amongst which BiVO₄-based processes are highly attractive due to their suitable band gap for solar-driven processes. However, the performance of BiVO₄ alone in this role is often unsatisfactory. Herein we report the improvement of BiVO₄ performance with reduced graphene oxide (rGO) as a co-catalyst for the photoelectrochemical water splitting (PEC-WS) in the presence of simple functionalized benzene derivatives (SFBDs), i.e., phenol (PH), benzoic acid (BA), salicylic acid (SA), and 5-aminosalicylic acid (5-ASA) as potential photogenerated hole scavengers from contaminated wastewaters. Linear sweep voltammetry and chronoamperometry, along with electrochemical impedance spectroscopy were utilized to elucidate PEC-WS performance under illumination. rGO has remarkably improved the performance of BiVO₄ in this role by decreasing photogenerated charge recombination. In addition, 5-ASA greatly improved current densities. After 120 min under LED illumination, 0.53 μmol of H₂ was produced. The type and concentration of SFBDs can have significant and at times opposite effects on the PEC-WS performance of both BiVO₄ and rGO-BiVO₄.