This minireview highlights recent advances on photocatalytic and electrocatalytic applications of doped CDs with improved electronic structures.

Development of high performances gas sensors to monitor and detect the volatile organic compound triethylamine is of paramount importance for health and environmental protection. The Co₃O₄-ZnO nanoparticles composite was successfully synthesized by the one-step hydrothermal route and annealing process in this work. The gas sensitivity test results show that the composite exhibits excellent triethylamine-sensing performance at a cobalt content of 1 at%, indicating potential application for triethylamine detection. The sensor based on the Co₃O₄-ZnO composite had higher sensitivity to triethylamine, better selectivity, and faster response recovery rate compared with pure ZnO sensor. Combined with the structural characteristics of the characterized Co₃O₄-ZnO nanocomposite, the optimized triethylamine sensing performances can be ascribed to the p-n heterojunction effect between Co₃O₄ and ZnO, as well as the catalytic and high oxygen adsorption properties of Co₃O₄.

A novel carboxymethyl cellulose (CMC)-supported graphene oxide aerogel (CGOA) was fabricated from a cost-effective and abundant bituminous coal by a mild hydrothermal process and freeze-drying treatment. Such an aerogel has cross-linked graphene oxide layers supported by CMC, and therefore, displays high mechanical strength while having ultra-low density (8.257 mg·cm⁻³). The CGOA has a 3D interconnected porous structure, beneficial graphene framework defects and abundant oxygen-containing functional groups, which offer favorable diffusion channels and effective adsorption sites for the transport and adsorption of dye molecules. The adsorption performance of rhodamine B by an optimized CGOA shows a maximum monolayer adsorption capacity of 312.50 mg·g⁻¹, as determined by Langmuir isotherm parameters. This CGOA exhibited a better adsorption efficiency (99.99%) in alkaline solution, and satisfactory stability (90.60%) after three cycles. In addition, adsorption experiments on various dyes have revealed that CGOA have better adsorption capacities for cationic dyes than anionic dyes.

A novel approach is developed to synthesize a nitrogen-doped porous Co₃O₄/anthracite-derived graphene (Co₃O₄/AG) nanocomposite through a combined self-assembly and heat treatment process using resource-rich anthracite as a carbonaceous precursor. The nanocomposite contains uniformly distributed Co₃O₄ nanoparticles with a size smaller than 8 nm on the surface of porous graphene, and exhibits a specific surface area (120 m²·g⁻¹), well-developed mesopores distributed at 3~10 nm, and a high level of nitrogen doping (5.4 at. %). These unique microstructure features of the nanocomposite can offer extra active sites and efficient pathways during the electrochemical reaction, which are conducive to improvement of the electrochemical performance for the anode material. The Co₃O₄/AG electrode possesses a high reversible capacity of 845 mAh·g⁻¹ and an excellent rate capacity of 587 mAh·g⁻¹. Furthermore, a good cyclic stability of 510 mAh·g⁻¹ after 100 cycles at 500 mA·g⁻¹ is maintained. Therefore, this work could provide an economical and effective route for the large-scale application of a Co₃O₄/AG nanocomposite as an excellent anode material in lithium-ion batteries.