Rizwan Shoukat

Dr. Rizwan Shoukat

orcid

Research Focus & Metrics

Academic Career Length

4Years (2023-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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3 January 2025 in Polymers
Verified
Journal Article
Open access
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RSRizwan Shoukat
Rizwan Shoukat
MCMarta Cappai
Marta Cappai
LPLuca Pilia
Luca Pilia
Giorgio PiaGiorgio Pia
Giorgio Pia
Starch is among the most abundant natural compounds in nature after cellulose. Studies have shown that the structure and functions of starch differ extensively across and among botanical types, isolation procedures, and climate factors, resulting in starch with significant variations in its chemical, physical, morphological, thermal, and functional characteristics. To enhance its beneficial properties and address inherent limitations, starch is modified through various techniques, resulting in significant alterations to its chemical and physical characteristics. These structural modifications impart considerable technological and industrial versatility. In the food sector, modified starch serves as a thickener, shelf-life extender, fat replacer, texture modifier, gelling agent, and stabilizer. In non-food applications, it functions as a sizing agent, binder, disintegrant, absorbent, and adhesive and is employed in construction as a sealant and to improve material bonding strength. The demand for modified starch has surpassed that of its native counterpart, reflecting its growing market value and the industry’s interest in products with novel functional attributes and enhanced value. This study focuses on rice starch, highlighting its structure and composition and their impact on physicochemical properties and functionality. Additionally, it examines the enhancement of its techno-functional characteristics, achieved through various modification processes.

29 June 2023 in Applied Sciences
Verified
Journal Article
Open access
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RSRizwan Shoukat
Rizwan Shoukat
MCMarta Cappai
Marta Cappai
Giorgio PiaGiorgio Pia
Giorgio Pia
LPLuca Pilia
Luca Pilia
The beneficial nutrients and biologically active ingredients extracted from plants have received great attention in the prevention and treatment of several diseases, including hypercholesterolemic, cancer, diabetes, cardiovascular disorders, hypoglycemic, hypolipidemic, edema, joint pain, weight control, eye vision problems, neuroprotective effects, and asthma. Highly active ingredients predominantly exist in fruit and cladodes, known as phytochemicals (rich contents of minerals, betalains, carbohydrates, vitamins, antioxidants, polyphenols, and taurine), which are renowned for their beneficial properties in relation to human health. Polyphenols are widely present in plants and have demonstrated pharmacological ability through their antimicrobial, anti-inflammatory, anti-bacterial, and antioxidant capacity, and the multi-role act of Opuntia ficus indica makes it suitable for current and future usage in cosmetics for moisturizing, skin improvement, and wound care, as healthful food for essential amino acids, as macro and micro elements for body growth, in building materials as an eco-friendly and sustainable material, as a bio-composite, and as an insulator. However, a more comprehensive understanding and extensive research on the diverse array of phytochemical properties of cactus pear are needed. This review therefore aims to gather and discuss the existing literature on the chemical composition and potential applications of cactus pear extracts, as well as highlight promising directions for future research on this valuable plant.

27 February 2024 in Sustainability
Verified
Journal Article
Open access
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SRShamas Riaz
Shamas Riaz
MAM. Shafiq Anjum
M. Shafiq Anjum
AAAbid Ali
Abid Ali
YMYasir Mehmood
Yasir Mehmood
MAMuhammad Ahmad
Muhammad Ahmad
RSRizwan Shoukat
Rizwan Shoukat
Hydrogen fuel is a clean and versatile energy carrier that can be used for various applications, including transportation, power generation, and industrial processes. Electrocatalytic water splitting could be the most beneficial and facile approach for producing hydrogen. In this work, transition metal selenide composites with carbon nanotubes (CNTs) have been investigated for electrocatalytic water splitting. The synthesis process involved the facile one-step hydrothermal growth of transition metal nanoparticles over the CNTs and acted as an efficient electrode toward electrochemical water splitting. Scanning electron microscopy and XRD patterns reveal that nanoparticles were firmly anchored on the CNTs, resulting in the formation of composites. The electrochemical measurements reveal that CNT composite with nickel–cobalt selenides (NiCo-Se/CNTs@NF) display remarkable oxygen evolution reaction (OER) activity in basic media, which is an important part of hydrogen production. It demonstrates the lowest overpotential (η10mAcm−2) of 0.560 V vs. RHE, a reduced Tafel slope of 163 mV/dec, and lower charge transfer impedance for the OER process. The multi-metallic selenide composite with CNTs demonstrating unique nanostructure and synergistic effects offers a promising platform for enhancing electrocatalytic OER performance and opens up new avenues for efficient energy conversion and storage applications.

23 February 2024 in Materials
Verified
Journal Article
Open access
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MCMarta Cappai
Marta Cappai
RSRizwan Shoukat
Rizwan Shoukat
LPLuca Pilia
Luca Pilia
Roberto RicciuRoberto Ricciu
Roberto Ricciu
DLDaniele Lai
Daniele Lai
Giorgio PiaGiorgio Pia
Giorgio Pia
The fight against climate change has delineated new objectives, among which one of the most crucial is the replacement of high-energy-intensity materials in the construction sector with more sustainable and thermally efficient alternatives to reduce indirect emissions. Consequently, the thermal properties of materials assume fundamental importance. In this regard, the large-scale use of earth represents a promising option, not only due to its widespread availability but especially for its minimal embodied energy. However, to enhance its durability, it is necessary to stabilize the mixtures of raw materials. This study analyzes experimental systems based on earth stabilized with bio-based polymers to evaluate their thermal properties and how these vary depending on the selected mix-design. The experimental measurements showed thermal properties comparable to conventional materials. As expected, thermal conductivity increases when porosity decreases. The minimum value is equal to 0.216 W/m·K vs. a porosity of 43.5%, while the maximum is 0.507 W/m·K vs. a porosity of 33.2%. However, the data obtained for individual systems may vary depending on the topological characteristics, which were analyzed through a model for granular materials. The modeling suggests correlations between microstructures and thermal behaviour, which can be useful to develop tools for the mix-design procedure.

13 October 2024 in Analytical Science Advances
Verified
Journal Article
Open access
AAAbid Ali
Abid Ali
RSRizwan Shoukat
Rizwan Shoukat
AAAhmad Raza Ashraf
Ahmad Raza Ashraf
ZRZarqa Rasheed
Zarqa Rasheed
SMSheza Muqaddas
Sheza Muqaddas
IMIsmail ElKamil Suliman Mohamed
Ismail ElKamil Suliman Mohamed
Glucose detection is critical in clinical health and the food industry, particularly in the diagnosis of blood sugar levels. Carbon‐based fiber materials have recently featured prominently as non‐enzymatic electrochemical glucose detectors. Herein, cobalt‐based ferrite (CoFe2O4) in the form of nanoparticles has been successfully fabricated over the carbon nanotubes (CNTs) fiber via a simple hydrothermal process. Fabricated microelectrode (CoFe2O4@CNTs) was investigated as an electrocatalyst toward the non‐enzymatic electrochemical glucose sensors. The structure and morphology of the modified fiber were studied by scanning electron microscopy including energy‐dispersive X‐ray spectroscopy. The electrochemical capability of the microelectrode was analyzed by using different electrochemical techniques including cyclic voltammetry, chronoamperometry, and electrochemical impedance spectroscopy (EIS). The proposed sensors exhibited a superb sensitivity of 0.21 µAcm−2 mM−1, a good linear range from 1 to 9 mM, and a lower detection limit of 1.7 mM. Further investigation via EIS indicated the low charge transfer resistance as compared to the bare CNTs‐based fiber. Outcomes revealed that the material can potentially prove promising for the disposable microelectrode toward electrochemical glucose sensing.

10 May 2025 in Analytical Science Advances
Verified
Journal Article
Open access
AKAmina Khalid
Amina Khalid
RSRizwan Shoukat
Rizwan Shoukat
AAAbid Ali
Abid Ali
SASalih Akyürekli
Salih Akyürekli
ASArfaa Sajid
Arfaa Sajid
AAAmel Y. Ahmed
Amel Y. Ahmed
A highly sensitive and stable nonenzymatic glucose biosensor has been developed via composite materials composed of CuO and graphene oxide (GO)/carbon nanotube (CNT) nanohybrid (CuO/GO/CNTs). Copper oxide nanoparticle(NP)‐modified CNTs were stacked via graphene sheets and synthesized through hydrothermal method, providing a larger surface area with boosted catalytic activity for efficient mass and electron passage, respectively. Scanning electron microscopy (SEM) and energy‐dispersive x‐ray (EDX) spectroscopy have been used to investigate the morphology and composition of as‐prepared nanohybrids, whereas x‐ray diffraction (XRD) patterns provide information about the crystal structure and lattice parameters. Fabricated nanohybrid was used as electrode material to develop the nonenzymatic glucose biosensor, which exhibited better performance with a linear dynamic range from 0.06 to 0.74 mM, a high sensitivity of 328 mA mM−1 cm−2 and a low detection limit of up to 0.033 mM with a fast response time of 2 s. Although the stability and reusability of the fabricated electrode have been tested. The limit of detection was determined by using the traditional formula LOD = (SNR × σ)/Slope. The outcomes recommend the synthesized novel structured nanohybrid as a promising material possessing significant impact for flexible and wearable biosensing applications.