Because of their excellent properties, glass-ceramics have been widely developed and applied in many fields, and there are many potential application values to be disseminated. The preparation of glass-ceramics from industrial slag and metallurgical waste provides a new way for the comprehensive utilization of solid waste. Coal gangue is the largest of all kinds of industrial waste slag, while iron tailings and high-carbon ferrochrome slag also occupy a large proportion of China’s industrial solid waste. With cheap industrial solid waste as the main raw material, the production of high-value-added glass-ceramics can reduce pollution, protect the ecological environment, and have good economic and social benefits. Cordierite glass-ceramics were prepared using the sintering method with coal gangue, iron tailings, and high-carbon ferrochrome slag as the main raw materials. Meanwhile, an iron silicon alloy containing chromium was obtained. The heat treatment system of basic glass was determined by differential scanning calorimetry (DSC), and the sintered product was analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). An orthogonal test was used to analyze the effects of the mass of basic glass powder, molding pressure, and holding time on the grain size and crystallinity of the samples. The hardness, acid and alkali resistance, density, and water absorption of the sintered products were determined. The results show that the main crystal phase of the prepared glass-ceramics is cordierite. The optimal combination for the green body is “basic glass powder mass 6 g, molding pressure 35 MPa, holding time 10 min”. The properties of glass-ceramics are good. At the crystallization temperature of 970 °C, the Vickers hardness is up to 866 HV, and the bulk density is up to 2.99 g/cm³. This study may provide a useful reference for the treatment of industrial solid waste.

The physical and chemical processes in the raceway zone of the COREX melter–gasifier express are similar to those inside the blast furnace. Based on the research achievements on blast furnaces, the unsteady numerical simulation of a gas-solid two-phase in the raceway was carried out by using computational fluid software. The formation process of the raceway in the COREX melter–gasifier was simulated. The shape and size of the raceway were obtained. Then, the effect of gas flow on the depth and height of the raceway was analyzed in this paper.

The pulverized lime/limestone injection by top oxygen blowing lance during the basic oxygen furnace (BOF) process has gained much interest in recent years due to its advantages in helping slag formation and consequently in promoting refining reactions such as dephosphorization. In this pneumatic process, understanding the motion behavior and distribution of the powder particles in the furnace is of importance for regulating and designing this refining system reliably and efficiently. In this study, limestone powder top blowing through a novel nozzles-twisted oxygen lance during a BOF process is proposed and the process is simulated by establishing a multi-fluid flow model. The coupled fluid flow of gaseous oxygen and liquid steel is predicted by the volume of fluid (VOF) method, and the motion of the limestone particles is tracked by the discrete phase model (DPM). The results show that the powder injection has little effect on cavity depth of the oxygen-powder mixture jets of the nozzles-twisted lance, but decreases cavity width. During the blowing process, most of the powder particles gather around hot spots while the rest are taken out of the furnace by the reflecting oxygen stream or penetrate into the molten bath. The generated swirling flow of the nozzles-twisted oxygen lance enables a decrease in the amount of the powder particles carried by the reflecting stream and going into the molten bath, through changing the motion paths of the powder particles. As a result, the concentration distribution of the powder particles in the molten bath varies. It could be suggested that for the limestone powder injection the preferred nozzle twist angle of the oxygen lance is 10° due to the favorable conditions for dephosphorization.

A two-dimensional water model was used to simulate the process of combined blowing. The effect of boundary conditions on the size and coordinate distribution of the dispersed phase was investigated. The results showed that the frequency of the dispersed phase at a certain size level is proportional to its size; the coordinates of the dispersed phase can be expressed in a dimensionless form that shows its uniformity of distribution. An empirical equation for the influence of the boundary conditions on the size and coordinate distribution of the dispersed phase in combined blowing process is also presented.

The use of direct reduced iron (DRI) in electric arc furnace (EAF) steelmaking has grown in popularity, yet dephosphorization, as a special concern because of high phosphorous levels, is yet to be fully understood. Here, a dynamic process model, accounting for phosphorus behavior under the circumstance of a continuous charge of raw materials and semi-continuous flushing slag in an industrial DRI-charged EAF, is developed and verified to predict trajectories of steel and slag phosphorus levels and slag chemistry in real time based on process conditions. The model is then employed to evaluate dephosphorization in a wide range of DRI phosphorus levels and process conditions. It is found that dephosphorization in industrial DRI-charged EAFs does not occur in equilibrium, with the phosphorus partition range of 20~70, compared to 130~170 for equilibrium conditions. For the phosphorus content in DRI, ranging from 0.02 wt.% to 0.2 wt.%, a dephosphorization ratio of more than 81% can be achieved at a slag basicity of 2.3. Dephosphorization is likely easily achieved even at a relatively low slag basicity of 1.5~1.7 when DRI containing phosphorus levels as high as ~0.1 wt.% is used, attaining a dephosphorization ratio of more than 70%. The current model can serve as a valuable tool, providing a knowledge base to assist in the design, operation, and optimization of DRI-charged EAF practices.