Because of their excellent properties, glass-ceramics have been widely developed and applied in many fields, and there are many potential application values to be disseminated. The preparation of glass-ceramics from industrial slag and metallurgical waste provides a new way for the comprehensive utilization of solid waste. Coal gangue is the largest of all kinds of industrial waste slag, while iron tailings and high-carbon ferrochrome slag also occupy a large proportion of China’s industrial solid waste. With cheap industrial solid waste as the main raw material, the production of high-value-added glass-ceramics can reduce pollution, protect the ecological environment, and have good economic and social benefits. Cordierite glass-ceramics were prepared using the sintering method with coal gangue, iron tailings, and high-carbon ferrochrome slag as the main raw materials. Meanwhile, an iron silicon alloy containing chromium was obtained. The heat treatment system of basic glass was determined by differential scanning calorimetry (DSC), and the sintered product was analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). An orthogonal test was used to analyze the effects of the mass of basic glass powder, molding pressure, and holding time on the grain size and crystallinity of the samples. The hardness, acid and alkali resistance, density, and water absorption of the sintered products were determined. The results show that the main crystal phase of the prepared glass-ceramics is cordierite. The optimal combination for the green body is “basic glass powder mass 6 g, molding pressure 35 MPa, holding time 10 min”. The properties of glass-ceramics are good. At the crystallization temperature of 970 °C, the Vickers hardness is up to 866 HV, and the bulk density is up to 2.99 g/cm³. This study may provide a useful reference for the treatment of industrial solid waste.

The pulverized lime/limestone injection by top oxygen blowing lance during the basic oxygen furnace (BOF) process has gained much interest in recent years due to its advantages in helping slag formation and consequently in promoting refining reactions such as dephosphorization. In this pneumatic process, understanding the motion behavior and distribution of the powder particles in the furnace is of importance for regulating and designing this refining system reliably and efficiently. In this study, limestone powder top blowing through a novel nozzles-twisted oxygen lance during a BOF process is proposed and the process is simulated by establishing a multi-fluid flow model. The coupled fluid flow of gaseous oxygen and liquid steel is predicted by the volume of fluid (VOF) method, and the motion of the limestone particles is tracked by the discrete phase model (DPM). The results show that the powder injection has little effect on cavity depth of the oxygen-powder mixture jets of the nozzles-twisted lance, but decreases cavity width. During the blowing process, most of the powder particles gather around hot spots while the rest are taken out of the furnace by the reflecting oxygen stream or penetrate into the molten bath. The generated swirling flow of the nozzles-twisted oxygen lance enables a decrease in the amount of the powder particles carried by the reflecting stream and going into the molten bath, through changing the motion paths of the powder particles. As a result, the concentration distribution of the powder particles in the molten bath varies. It could be suggested that for the limestone powder injection the preferred nozzle twist angle of the oxygen lance is 10° due to the favorable conditions for dephosphorization.

The physical and chemical processes in the raceway zone of the COREX melter–gasifier express are similar to those inside the blast furnace. Based on the research achievements on blast furnaces, the unsteady numerical simulation of a gas-solid two-phase in the raceway was carried out by using computational fluid software. The formation process of the raceway in the COREX melter–gasifier was simulated. The shape and size of the raceway were obtained. Then, the effect of gas flow on the depth and height of the raceway was analyzed in this paper.

A mathematical model is proposed to analysis low-velocity gas–powder flow in a packed bed. The model, as an extension of the two-fluid model, consider the interactions between gas, powder and packed particles, as well as the static and dynamic holdups of powder. What's more, the sticking rate and departing rate of powder, which are derived from the filtration mechanisms, are also included in the powder phase's continuity equation. The validation of the present model is performed by comparing the simulated results with the previous experimental. On this basis, the flow characteristics of low-velocity gas–powder flow in a packed bed with lateral inlet are analysed, and the effect of gas velocity and powder mass flux on static holdup of powder have also been investigated.