Silane coupling agents (SCAs) with different organofunctional groups were coated on the surfaces of Al₂O₃ ceramic particles through hydrolysis and condensation reactions, and the SCA-coated Al₂O₃ ceramic particles were dispersed in a commercial photopolymer based on interpenetrating networks (IPNs). The organofunctional groups that have high radical reactivity and are more effective in UV curing systems are usually functional groups based on acryl, such as acryloxy groups, methacrloxy groups, and acrylamide groups, and these silane coupling agents seem to improve interfacial adhesion and dispersion stability. The coating morphology and the coating thickness distribution of SCA-coated Al₂O₃ ceramic particles according to the different organofunctional groups were observed by FE-TEM. The initial dispersibility and dispersion stability of the SCA-coated Al₂O₃/High-temp composite solutions were investigated by relaxation NMR and Turbiscan. The rheological properties of the composite solutions were investigated by viscoelastic analysis and the mechanical properties of 3D-printed objects were observed with a nanoindenter.

In an effort to fabricate a wearable piezoelectric energy harvester based on core-shell piezoelectric yarns with external electrodes, flexible piezoelectric nanofibers of BNT-ST (0.78Bi_0.5Na_0.5TiO₃-0.22SrTiO₃) and polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) were initially electrospun. Subsequently, core-shell piezoelectric nanofiber yarns were prepared by twining the yarns around a conductive thread. To create the outer electrode layers, the core-shell piezoelectric nanofiber yarns were braided with conductive thread. Core-shell piezoelectric nanofiber yarns with external electrodes were then directly stitched onto the fabric. In bending tests, the output voltages were investigated according to the total length, effective area, and stitching interval of the piezoelectric yarns. Stitching patterns of the piezoelectric yarns on the fabric were optimized based on these results. The output voltages of the stitched piezoelectric yarns on the fabric were improved with an increase in the pressure, and the output voltage characteristics were investigated according to various body movements of bending and pressing conditions.

A 3YSZ (3 mol% yttria-stabilized zirconia) ceramic green body with 50 vol% of ceramic content was 3D-printed by supportless stereolithography under optimal drying, debinding, and sintering conditions in order to achieve high strength and density. The viscosity and flowability of the ceramic nanocomposite resins were optimized by adjusting the amounts of non-reactive diluents. The ceramic 3D-printed objects have a high polymer content compared to ceramics samples manufactured by conventional manufacturing processes, and the attraction between layers is weak because of the layer-by-layer additive method. This causes problems such as layer separation and cracking due to internal stress generated when materials such as solvents and polymers are separated from the objects during the drying and debinding processes; therefore, the drying and debinding conditions of 3YSZ ceramic 3D-printed objects were optimized based on thermogravimetry–differential thermal analysis. The sintering conditions at various temperatures and times were analyzed using X-ray diffraction, SEM, and flexural strength analysis, and the body of the 3YSZ ceramic 3D-printed object that sintered at 1450 °C for 150 min had a relative density of 99.95% and flexural strength of 1008.5 MPa. This study widens the possibility of manufacturing ceramic 3D-printed objects with complex shapes, remarkable strength, and unique functionality, enabling their application in various industrial fields.

Piezoelectric nanofiber composites of polyvinylidene fluoride (PVDF) polymer and PZT (Pb(Zr_0.53Ti_0.47)O₃) ceramics were fabricated by electrospinning. The microstructure of the PZT/PVDF electrospun nanofiber composites was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The tensile properties (stress-strain curves) and electrical properties (P-E hysteresis loops) of the PZT/PVDF electrospun nanofiber composites were investigated as a function of PZT content from 0 wt% to 30 wt%. The results demonstrated that a PZT content of 20 wt% had enhanced tensile and piezoelectric characteristics.

Flexible lead-free piezoelectric nanofibers, based on BNT-ST (0.78Bi_0.5Na_0.5TiO₃-0.22SrTiO₃) ceramic and poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) copolymers, were fabricated by an electrospinning method and the effects of the degree of alignment in the nanofibers on the piezoelectric characteristics were investigated. The microstructure of the lead-free piezoelectric nanofibers was observed by field emission scanning electron microscope (FE-SEM) and the orientation was analyzed by fast Fourier transform (FFT) images. X-ray diffraction (XRD) analysis confirmed that the phase was not changed by the electrospinning process and maintained a perovskite phase. Polarization-electric field (P-E) loops and piezoresponse force microscopy (PFM) were used to investigate the piezoelectric properties of the piezoelectric nanofibers, according to the degree of alignment—the well aligned piezoelectric nanofibers had higher piezoelectric properties. Furthermore, the output voltage of the aligned lead-free piezoelectric nanofibers was measured according to the vibration frequency and the bending motion and the aligned piezoelectric nanofibers with a collector rotation speed of 1500 rpm performed the best.