Heat-injection production is a common technique for gas-hydrate development, and the mechanism needs further in-depth study, particularly of the decomposition characteristics of natural-gas hydrate, which are important fundamental issues. The natural gas-hydrate-reservoir model is based on a mathematical description of reservoir properties that considers the effects of hydrate decomposition and reservoir stress conditions. The aim of our investigation was to analyze the production and decomposition characteristics of natural-gas hydrates based on the results of numerical simulations of heat-injection production. The effects of different heat-injection temperatures and heat-injection rates on production were compared, and the decomposition characteristics of hydrates were evaluated qualitatively and characterized quantitatively by temperature distribution, saturation distribution, and the decomposition front in the process of heat-injection production of natural-gas hydrate. The results showed that, with the increase in the heat-injection temperature, the decomposition front moved faster, the area share of decomposition zone increased, but the increase extent decreased. The high heat-injection rate had a more significant effect than the heat-injection temperature in promoting the decomposition of natural-gas hydrate.

Research progress of carbon dioxide applied for methane exploitation from hydrates is summarized, with a focus on advances in molecular dynamics simulations and their application in understanding the mechanism of carbon dioxide replacement for hydrate exploitation. The potential of carbon dioxide in enhancing energy recovery efficiency and promoting carbon capture and storage is emphasized. An overview is provided of the advancements made in utilizing carbon dioxide for methane hydrate exploitation, highlighting its significance. Subsequently, the theoretical foundations and techniques of molecular dynamics simulations are delved into, encompassing key elements such as statistical ensembles, molecular force fields, and numerical solution methods. Through simulations, various characterization parameters including mean square displacement, radial distribution functions, coordination numbers, angular order parameters, and hydrogen bonds are computed and analyzed, which are crucial for understanding the dynamic changes in hydrate structures and the replacement process. Thorough research and analysis have been conducted on the two possible and widely debated mechanisms involved in the replacement of methane hydrates by carbon dioxide, with a particular emphasis on guest molecular replacement and hydrate reconfiguration. These processes encompass the intricate interactions between carbon dioxide molecules and the cage-like structure of hydrates, as well as the rearrangement and stabilization of hydrate structures. Several key issues surrounding the application of carbon dioxide for methane hydrate exploitation are identified, including the influence of thermodynamic conditions, the selection of auxiliary gases, and other potential factors such as geological conditions and fluid properties. Addressing these issues is crucial for optimizing the extraction process and enhancing economic and environmental benefits. A theoretical foundation and technical reference for the application of carbon dioxide in methane hydrate exploitation are provided, while future research directions and priorities are also outlined.