Karst features such as polje are highly vulnerable to natural and anthropogenic pollution. The main objectives of this study were to investigate the soil quality in the Ioannina polje (north-west Greece) concerning arsenic (As) and zinc (Zn), and delineate their origin as well as compare the As and Zn content in soil with criteria recorded in the literature. For this purpose, the geomorphological settings, the land use, and the soil physicochemical properties were mapped and evaluated, including soil texture and concentrations of aqua-regia extractable As and Zn. The concentration of elements was spatially correlated with the land use and the geology of the study area, while screening values were applied to assess land suitability. The results reveal that 72% of the total study area has a very gentle slope. This relief favors urban and agricultural activity. Thus, the urban and agricultural land used cover 92% of the total area. The spatial distribution for As and Zn in the soil of the study area is located on very gentle slopes and is strongly correlated with the geological parent materials and human-induced contamination sources. Arsenic and Zn can be considered enriched in the soil of the area studied. The median topsoil contents (in mg kg⁻¹) for As (agricultural soil 16.0; urban soil 17.8) and Zn (agricultural soil 92.0; urban soil 95.0) are higher compared to the corresponding median values of European topsoils. Land evaluation suitability concerning criteria given from the literature is discussed. The proposed work may be helpful in the project of land use planning and the protection of the natural environment.

Assessing the suitability of urban and agricultural land is essential for planning sustainable urban and agricultural systems. The main objective of this study is to evaluate the suitability of land in Ioannina plain (western Greece) concerning the soil contents of two potentially toxic elements, cadmium (Cd) and cobalt (Co). Geochemical and spatial analysis methods were applied to assess the distribution of Cd and Co in the soil of the Ioannina plain and identify their origin. The primary anthropogenic sources of Cd and Co in the topsoil of the study area can be attributed to traffic emissions, aircraft operations, vehicle crushing and dismantling activities. Element content is compared to international guidelines and screening values. Cadmium and Co concentration in the soil of the study area is well above the European topsoil mean. Thus, the urban and agricultural lands cover the vast majority (92%) of the total area. Cadmium concentration in soil of the study area with a mean (mg kg⁻¹) 1.7 and 2.0 was observed in agricultural and urban land use, respectively. Cobalt content in soil of the area studied with a mean (mg kg⁻¹) 30.8 and 37.1 was recorded in agricultural and urban land use, respectively. Land evaluation suitability by adopting criteria provided from the international literature is discussed.

The primary goal of this study is to analyze the hydrogeochemical properties and assess the groundwater quality for drinking, domestic, and irrigation purposes in West El Minia, Egypt. Major components were determined in 49 groundwater samples to evaluate water quality in the study area. Principal component analysis (PCA), hierarchical cluster analysis (HCA), geostatistics, and spatial mapping were used to identify the chemical components and processes that influence groundwater quality and highlight areas of health risks. According to the TDS values, about 22% of the groundwater samples are suitable for drinking. Due to the elevated values of hardness in the examined water, none of the water samples are suitable for use in a household. The majority of groundwater samples are acceptable for irrigation based on the sodium adsorption ratio (SAR), residual sodium carbonate (RSC), Kelley ratio (KR), magnesium hazard (MH), and permeability index, and some can be adequately treated. The study indicated that different groundwater characteristics (such as TDS, Na⁺, K⁺, HCO₃⁻, Cl⁻, and SO₄²⁻) do not comply with WHO requirements in some regions, which may pose a threat to human health.

The composition of sediments and other materials occurring in streams, geochemical processes within the drainage basin, and various land uses are among the main factors influencing stream water composition. Stream sediment and wildfire ash samples were gathered from the area studied. The applied methodology consists of aqua regia and Diethylene-Triamine-Penta-Acetic acid (DTPA) chemical extraction; Cation Exchange Capacity (CEC), pH, and soil organic matter (OM) determination; a Geographic Information System (GIS) database; factor analysis; and determination of the contamination factor (CF) for the assessment of contamination degree. This study aimed to evaluate the elements’ content in stream sediments of Kineta and Nea Peramos areas (West Attica, Greece) and investigate any relationship between elements (aqua regia and DTPA extracted) in stream sediment and ash in wildfire and flood-impacted areas. The stream sediments’ properties, the bioavailable forms of copper (Cu), iron (Fe), manganese (Mn) and zinc (Zn), and the total content of other potentially toxic elements in wildfire ash samples, are discussed. This research estimated moderate contamination for Fe_DTPA, Mn_DTPA and Zn_DTPA in stream sediments of the study area. Contamination for Cu_DTPA and moderate contamination for Zn_DTPA in the stream sediments of the Nea Peramos area was recorded. Factor analysis results suggested that the contents of Fe_DTPA, Mn_DTPA, Cu_DTPA and Zn_DTPA in the study area’s stream sediments may affect the chemistry of stream water.

The present study focused on the Upper Cretaceous to Middle Miocene sequence in the Central Gulf of Suez, Egypt. The Upper Cretaceous to Middle Miocene sequence in the October field is thick and deeply buried, consisting mainly of brown limestone, chalk limestone, and reefal limestone intercalated with clastic shale. This study integrated various datasets, including total organic carbon (TOC), Rock-Eval pyrolysis, visual kerogen examination, vitrinite reflectance (%Ro), and bottom-hole temperature measurements. The main objective of this study is to delineate the source rock characteristics of these strata regarding organic richness, thermal maturity, kerogen type, timing of hydrocarbon transformation and generation. The Upper Cretaceous Brown Limestone Formation is represented by 135 samples from four wells and is considered to be a fair to excellent source rock, primarily containing type I and II kerogen. It is immature to early mature, generating oil with a low to intermediate level of hydrocarbon conversion. The Eocene Thebes Formation is represented by 105 samples from six wells and is considered to be a good to fair oil source rock with some potential for gas, primarily containing type II and II/III kerogen. Most samples are immature with a low level of hydrocarbon conversion while few are mature having an intermediate degree of hydrocarbon conversion. The Middle Miocene Lower Rudeis Formation is represented by 8 samples from two wells and considered to be a fair but immature source rock, primarily containing type III kerogen with a low level of conversion representing a potential source for gas. The Middle Miocene Belayim Formation is represented by 29 samples from three wells and is considered to be a poor to good source rock, primarily containing kerogen type II and III. Most samples are immature with a low level of hydrocarbon conversion while few are mature having an intermediate degree of hydrocarbon conversion. 1D basin model A-5 well shows that the Upper Cretaceous Brown Limestone source rock entered the early oil window at 39 Ma, progressed to the main oil window by 13 Ma, and remains in this stage today. The Eocene Thebes source rock began generating hydrocarbons at 21.3 Ma, advanced to the main oil window at 11 Ma, and has been in the late oil window since 1.6 Ma. The Middle Miocene Lower Rudeis source rock entered the early oil window at 12.6 Ma, transitioned to the main oil window at 5.7 Ma, where it remains active. In contrast, the Middle Miocene Belayim source rock has not yet reached the early oil window and remains immature, with values ranging from 0.00 to 0.55 % Ro. The transformation ratio plot shows that the Brown Limestone Formation began transforming into the Upper Cretaceous (73 Ma), reaching 29.84% by the Miocene (14.3 Ma). The Thebes Formation initiated transformation in the Late Eocene (52.3 Ma) and reached 6.42% by 16.4 Ma. The Lower Rudeis Formation began in the Middle Miocene (18.7 Ma), reaching 3.59% by 9.2 Ma. The Belayim Formation started its transformation at 11.2 Ma, reaching 0.63% by 6.8 Ma.