We performed complex conductivity measurements on 28 core samples from the hole drilled for the Humu'ula Groundwater Research Project (Hawai'i Island, HI, USA). The complex conductivity measurements were performed at 4 different pore water conductivities (0.07, 0.5, 1.0 or 2.0, and 10 S m−1 prepared with NaCl) over the frequency range 1 mHz to 45 kHz at 22 ± 1 °C. The in-phase conductivity data are plotted against the pore water conductivity to determine, sample by sample, the intrinsic formation factor and the surface conductivity. The intrinsic formation factor is related to porosity by Archie's law with an average value of the cementation exponent m of 2.45, indicating that only a small fraction of the connected pore space controls the transport properties. Both the surface and quadrature conductivities are found to be linearly related to the cation exchange capacity of the material, which was measured with the cobalt hexamine chloride method. Surface and quadrature conductivities are found to be proportional to each other like for sedimentary siliclastic rocks. A Stern layer polarization model is used to explain these experimental results. Despite the fact that the samples contain some magnetite (up to 5 per cent wt.), we were not able to identify the effect of this mineral on the complex conductivity spectra. These results are very encouraging in showing that galvanometric induced polarization measurements can be used in volcanic areas to separate the bulk from the surface conductivity and therefore to define some alteration attributes. Such a goal cannot be achieved with resistivity alone.
We investigate the relationship between complex conductivity spectra and both permeability and pore mean size and distribution of 22 core samples (21 volcanic rocks and 1 clayey sandstone). The volcanic core samples were extracted from a wellbore drilled for the Humu‘ula Groundwater Research Project in the Humu‘ula saddle region between Mauna Kea and Mauna Loa volcanoes (Hawaii). The quadrature conductivity spectra of volcanic rocks exhibit a subtle, but generally detectable, relaxation frequency in the range 0.3 Hz to 45 kHz similar to the relaxation frequency observed for clayey sandstones. We find a fair relationship between this relaxation frequency and the pore size determined by mercury porosimetry. Combined with the intrinsic formation factor of the core samples, the relaxation frequency can be used as an indicator of the permeability of the material. The predicted values of the permeability are grossly consistent with the permeability values to air (in the range 0.001–100 mD) within two orders of magnitude. The measured permeability values are highly correlated to the peak of the pore size distribution determined from mercury porosimetry divided by the intrinsic formation factor. By fitting the complex conductivity spectra with the pore size distribution, we obtain the normalized chargeability of the core samples, which is, in turn, highly correlated to the measured cation exchange capacity.
1 July 2017 in Journal of Volcanology and Geothermal Research
Passive radio-frequency identification (RFID) was recently used to monitor landslide displacement at a high spatio-temporal resolution but only measured 1D displacement. This study demonstrates the tracking of 2D displacements, using an array of antennas connected to an RFID interrogator. Ten tags were deployed on a landslide for 12 months and 2D relative localization was performed using a phase-of-arrival approach. A period of landslide activity was monitored through RFID and displacements were confirmed by reference measurements. The tags showed displacements of up to 1.2 m over the monitored period. The centimeter-scale accuracy of the technique was confirmed experimentally and theoretically for horizontal localization by developing a measurement model that included antenna and tag positions, as well as multipath interference. This study confirms that 2D landslide displacement tracking with RFID is feasible at relatively low instrumental and maintenance cost.
27 December 2017 in IEEE Journal of Radio Frequency Identification
This paper investigates meteorological factors that affect the phase of radio-frequency identification (RFID) passive tags at 868 MHz, in outdoor conditions. The study identifies the effect of water on the tag and base antennas, the effect of temperature on the cables, tags, and base antenna, the effect of the tag support moisture, and the effect of atmospheric conditions on wave velocity. Combined, these effects could lead to over 8.1 radians phase drift over a year, in a typical environment. In a tag location tracking application, that would correspond to an error of 22 cm. This paper proposes techniques to correct these effects and to increase the phase stability. These techniques are applied to a new RFID system, which is tested in outdoor conditions, for five months. The new system improves the phase stability for rainy days, dry days, and long-term drift by a factor of 3, 12, and 5, respectively. After corrections, the long-term drift was reduced to below 0.05 radians per month, which corresponds to 1.5 millimeter per month.