Rapidly prepared SrS:Eu ²⁺ ,RE ³⁺ exhibits long red persistent luminescence independent of the rare earth co-dopant due to a high Schottky defect concentration.

Some copper(II) and zinc(II) complexes with oxindolimine ligands were tested regarding their trypanocidal properties. These complexes have already shown good biological activity in the inhibition of tumor cell proliferation, having DNA and mitochondria as main targets, through an oxidative mechanism, and inducing apoptosis. Herein, we demonstrate that they also have significant activity against the infective trypomastigote forms and the intracellular amastigote forms of T. cruzi, modulated by the metal ion as well as by the oxindolimine ligand. Selective indexes (LC₅₀/IC₅₀) determined for both zinc(II) and copper(II) complexes, are higher after 24 or 48 h incubation with trypomastigotes, in comparison to traditional drugs used in clinics, such as benznidazole, and other metal-based compounds previously reported in the literature. Additionally, tests against amastigotes indicated infection index <10% (% of infected macrophages/average number of amastigotes per macrophage), after 24 or 48 h in the presence of zinc(II) (60–80 µM) or analogous copper(II) complexes (10–25 µM). The copper complexes exhibit further oxidative properties, being able to damage DNA, proteins and carbohydrates, in the presence of hydrogen peroxide, with the generation of hydroxyl radicals. This redox reactivity could explain its better performance towards the parasites in relation to the zinc analogs. However, both copper and zinc complexes display good selective indexes, indicating that the influence of the ligand is also crucial, and is probably related to the inhibition of some crucial proteins.

Acrylonitrile-butadiene-styrene (ABS) is a thermoplastic copolymer commonly used in the electronics, automotive, and construction industries. In the aquatic environment, the formation of microplastics from larger-sized plastic waste occurs naturally, induced by physical, chemical, and biological processes that promote the aging of these particles. Here, we investigated the interactions between the freshwater amphipod Hyalella azteca and ABS microplastics (10-20 μm) (pristine and after accelerated aging) over 7 days of exposure. At the end of the exposure period, we evaluated the ability of H. azteca to fragment the ABS particles, as well as the changes in its oxidative stress biomarkers (SOD, CAT, MDA, and GST) as the result of ABS exposure. H. azteca promoted a significant fragmentation of ABS particles. The ratio of this biofragmentation was more pronounced in pristine particles. Despite the absence of significant changes in the mortality of exposed organisms, alterations in the oxidative stress biomarkers were observed. The results demonstrate the ability of H. azteca to fragment pristine and aged ABS microplastics and, the consequent susceptibility of these organisms to the effects of microplastic exposure.