Diwakar Karuppiah

Dr. Diwakar Karuppiah


Research Focus & Metrics

Academic Career Length

4Years (2023-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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7 February 2023 in Batteries
Verified
Journal Article
Open access
PDF file
PMPalanivel Molaiyan
Palanivel Molaiyan
GRGlaydson Simoes dos Reis
Glaydson Simoes dos Reis
DKDiwakar Karuppiah
Diwakar Karuppiah
Chandrasekar Mayandi SubramaniyamChandrasekar Mayandi Subramaniyam
Chandrasekar Mayandi Subramaniyam
FAFlaviano Garcia Alvarado
Flaviano Garcia Alvarado
Ulla LassiUlla Lassi
Ulla Lassi
Batteries are the backbones of the sustainable energy transition for stationary off-grid, portable electronic devices, and plug-in electric vehicle applications. Both lithium-ion batteries (LIBs) and sodium-ion batteries (NIBs), most commonly rely on carbon-based anode materials and are usually derived from non-renewable sources such as fossil deposits. Biomass-derived carbon materials are extensively researched as efficient and sustainable anode candidates for LIBs and NIBs. The main purpose of this perspective is to brief the use of biomass residues for the preparation of carbon anodes for LIBs and NIBs annexed to the biomass-derived carbon physicochemical structures and their aligned electrochemical properties. In addition, an outlook and some challenges faced in this promising area of research is presented. This review enlightens the readers with valuable insights and a reasonable understanding of issues and challenges faced in the preparation, physicochemical properties, and application of biomass-derived carbon materials as anode candidates for LIBs and NIBs.

13 November 2023 in Batteries
Verified
Journal Article
Open access
PDF file
DKDiwakar Karuppiah
Diwakar Karuppiah
DKDmitrii Komissarenko
Dmitrii Komissarenko
NYNur Sena Yuzbasi
Nur Sena Yuzbasi
YLYang Liu
Yang Liu
PSPradeep Vallachira Warriam Sasikumar
Pradeep Vallachira Warriam Sasikumar
Gurdial BluganGurdial Blugan
Gurdial Blugan
An inorganic solid electrolyte is the most favorable candidate for replacing flammable liquid electrolytes in lithium batteries. Lithium lanthanum zirconium oxide (LLZO) is considered a promising solid electrolyte due to its safe operating potential window (0–5 V) combined with its good electrochemical stability. In this work, 250 g batches of pre-sintered Ta-doped LLZO (Li7La3Zr1.6Ta0.4O12, Ta-LLZO) were synthesized for bulk production of a dense LLZO electrolyte. A simple two-step thermal treatment process was developed. The first thermal step at 950 °C initiates nucleation of LLZO, with carefully controlled process parameters such as heating atmosphere, temperature, and dopant concentration. In the second thermal step at 1150 °C, sintered discs were obtained as solid electrolytes, with relative densities of 96%. X-ray diffraction analysis confirmed the phase purity of the sintered Ta-LLZO disc, and refined data were used to calculate the lattice parameter (12.944 Å). Furthermore, the presence of the Ta dopant in the disc was confirmed through X-ray photoelectron spectroscopy (XPS) analysis. The ionic and electronic conductivity values of the Ta-LLZO disc were 10−4 S cm−1 and 10−10 S cm−1, respectively. These values confirm that the prepared (Ta-LLZO) discs exhibit ionic conductivity while being electronically insulating, being suitable for use as solid electrolytes with the requisite electrical properties.