Zeolites have been increasingly applied in various fields such as energy conversion, environmental remediation, chemical production, and so on, being used as membranes, catalysts, and supports due to their large specific areas and strong gas adsorption. And, developing low-cost strategies for the preparation of zeolites has attracted the extensive attention of researchers. Coal fly ash, waste glass, discard zeolites, and slags are typical industrial wastes and rich in Si and Al, indicating that these industrial wastes can be utilized as alternative raw materials of zeolite synthesis. Firstly, the chemical composition and properties of these industrial wastes are summarized. Then, the strategies involved in synthesizing different zeolites from various industrial wastes are discussed. In addition, the applications of these zeolites are comprehensively reviewed.
27 January 2020 in International Journal of Applied Glass Science
The increase in CO2 emissions has been identified as a core driving factor in the intensification of the greenhouse effect. In order to achieve the dual-carbon vision, research on CO2 capture and its catalytic conversion is receiving growing attention. Due to the high chemical stability of CO2 itself, traditional separation technologies find it difficult to capture it onto catalysts. Currently, using hydrocarbons as carriers for catalytic reactions is the most common and efficient method. In recent years, metal-organic frameworks (MOFs) have shown their irreplaceable importance in CO2 capture and catalytic conversion due to their unique adjustable and controllable pore structures and multiple active sites. This study integrates various classification criteria of MOFs, proposes a cooperative mechanism between metal doping and functional groups, and also reveals the CO2 capture and catalytic conversion processes. In addition, we have conducted an in-depth discussion on the future development of continuous-flow microreactor technology and provided performance and property relationship diagrams for multiple MOF series, offering valuable reference material for future research in related fields.
Nitrogen oxides (NOx) are very common air pollutants that are harmful to the environment and human bodies. Selective catalytic reduction with ammonia (NH3-SCR) is considered an effective means to remove NOx emissions due to its good environmental adaptability, high catalytic activity, and remarkable selectivity. In this paper, the preparation methods, types, advantages, and challenges of ZSM-5 catalysts are reviewed. Special attention is paid to the catalytic properties and influence factors of ZSM-5 catalysts for NH3-SCR. The SCR performances of ZSM-5 catalysts doped with single or multiple metal ions are also reviewed. In addition, the environmental adaptabilities (sulfur resistance, alkali resistance, water resistance, and hydrothermal stability) of ZSM-5 catalysts are discussed, and the development of ZSM-5 catalysts in denitrification is summarized.
Zeolites are porous materials with plentiful and adjustable pore structures, which are widely applied in various fields such as fossil fuel energy conversion, preparation of clean energy, chemical product conversion, CO2 capture, VOC treatment, and so on. Zeolites exhibited advantageous adsorption compared with traditional adsorbents such as activated carbon; in addition, they can also provide abundant reaction sites for various molecules. The chemical composition, structural acidity, and distribution of pore size can distinctly affect the efficiency of the reaction. The modification of zeolite structure, the development of novel and efficient preparation methods, as well as the improvement of reaction efficiency, have always been the focus of research for zeolites.