The performance of passivated emitter and rear (PERC) solar cells made of p-type Si wafers is often limited by recombination in the phosphorus-doped emitter. To overcome this limitation, a realistic PERC solar cell is simulated, whereby the conventional phosphorus-doped emitter is replaced by a thin, crystalline gallium phosphide (GaP) layer. The resulting GaP/Si PERC cell is compared to Si PERC cells, which have (i) a standard POCl₃ diffused emitter, (ii) a solid-state diffused emitter, or (iii) a high efficiency ion-implanted emitter. The maximum efficiencies for these realistic PERC cells are between 20.5% and 21.2% for the phosphorus-doped emitters (i)–(iii), and up to 21.6% for the GaP emitter. The major advantage of this GaP hetero-emitter is a significantly reduced recombination loss, resulting in a higher V_oc. This is so because the high valence band offset between GaP and Si acts as a nearly ideal minority carrier blocker. This effect is comparable to amorphous Si. However, the GaP layer can be contacted with metal fingers like crystalline Si, so no conductive oxide is necessary. Compared to the conventional PERC structure, the GaP/Si PERC cell requires a lower Si base doping density, which reduces the impact of the boron-oxygen complexes. Despite the lower base doping, fewer rear local contacts are necessary. This is so because the GaP emitter shows reduced recombination, leading to a higher minority electron density in the base and, in turn, to a higher base conductivity.

The rapid growth of the energy and transport sectors has led to an increase in fuel consumption, resulting in a significant rise in greenhouse gas emissions. Switching to renewable energy sources and replacing internal combustion engines with electric vehicles (EVs) can significantly reduce greenhouse gas emissions. In recent years, the electrification of the transportation sector has become a primary focus of research and development efforts. However, if EVs are charged using conventional energy sources, we are unable to fully capitalize on their potential to reduce emissions. Charging EVs using renewable energy sources is the optimal solution. Otherwise, the increased number of EVs on the roads can significantly impact the stability of existing electric grids. As a result, smart homes with EV charging stations are becoming increasingly popular worldwide. This review focuses on the concept of grid-connected rooftop solar photovoltaic (PV) smart homes integrated with EVs and energy management systems in Australia. Australia can reduce emissions in the building and transport sectors by electrifying a range of vehicles and ultimately powering them with 100% renewable energy sources. The benefits of EV integration alongside rooftop solar systems for smart homes with house-to-vehicle or vehicle-to-house, as well as vehicle-to-grid or grid-to-vehicle (bidirectional EV charging) capabilities are also explored in this article. By adopting these systems, these smart homes can provide energy schemes for commercial use, ultimately contributing to the owner’s economic benefit.