There have been many reports about the thickening ability of nanoparticles on the wormlike micelles in the recent years. Through the addition of nanoparticles, the viscosity of wormlike micelles can be increased. There still exists a doubt: can viscosity be increased further by adding more nanoparticles? To answer this issue, in this work, the effects of silica nanoparticles and temperature on the nanoparticles-enhanced wormlike micellar system (NEWMS) were studied. The typical wormlike micelles (wormlike micelles) are prepared by 50 mM cetyltrimethyl ammonium bromide (CTAB) and 60 mM sodium salicylate (NaSal). The rheological results show the increase of viscoelasticity in NEWMS by adding nanoparticles, with the increase of zero-shear viscosity and relaxation time. However, with the further increase of nanoparticles, an interesting phenomenon appears. The zero-shear viscosity and relaxation time reach the maximum and begin to decrease. The results show a slight increasing trend for the contour length of wormlike micelles by adding nanoparticles, while no obvious effect on the entanglement and mesh size. In addition, with the increase of temperature, remarkable reduction of contour length and relaxation time can be observed from the calculation. NEWMS constantly retain better viscoelasticity compared with conventional wormlike micelles without silica nanoparticles. According to the Arrhenius equation, the activation energy Ea shows the same increase trend of NEWMS. Finally, a mechanism is proposed to explain this interesting phenomenon.
Nanofluids have increasingly drawn interest in recent years with their various applications in a number of fields. The method for the preparation of stable nanofluids is a key concern for extending the application of nanofluids. This study focuses on the effect of pH, dosage of surfactant (TX-100), and nanofluid concentration on the stability of a silica nanofluid. Particle size and zeta potential are two important factors to consider in evaluating the stability of the silica nanofluid. Results indicate that the stability of the silica nanofluid highly depends on pH, dosage of surfactant (TX-100), and nanofluid concentration. On the basis of these experiments, the best conditions for the preparation of a silica nanofluid are 0.1 wt. % for the concentration of silica nanoparticles and TX-100 and 10 for pH. A transparent and stable silica nanofluid can thus be obtained.