The analysis of food salt is very important because of its high consumption by the population, for both medicinal and nutritional use. In this study, nine different samples of food salt (Cyprus black, Himalayan pink, Hawaii red, iodized, hyposodic iodized, Maldon smoked sea, common sea, Breton sea and Persia blue), coming from large Italian retailers and employed by people for different cooking food purposes, were investigated through High Purity Germanium (HPGe) Gamma Spectrometry in order to evaluate the anthropogenic (¹³⁷Cs) and natural (⁴⁰K) radioisotopes activity concentration, and used Inductively Coupled Plasma Mass Spectrometry (ICP-MS) in order to assess any possible metals contamination by a comparison between Cu, As, Cd, Hg and Pb concentrations and the limits set by the Italian Legislation. The evaluation of dose levels due to the salt ingestion for the age category higher than 17 years was performed taking into account the human body daily need of about 10 g of salt, and in the precautionary hypothesis, this need was satisfied from a single type of salt. All obtained results are under allowable levels (1 mSv/year), thus excluding the risk of ionizing radiation effects on humans. Regarding to the metals concentration, experimental results show that it is lower than the contamination threshold values, thus excluding their presence as pollutants.

In the present article, a case study is reported regarding an investigation carried out in order to assess radioactivity concentration, heavy metals pollution and mineralogy of a beach stretch extending from Soverato to Squillace municipalities of the Ionian coast of Calabria, South of Italy, a popular tourist destination, especially in summer. The analysis of radionuclides contents was performed by using a High Purity Germanium (HPGe) gamma-ray detector, in order to quantify the average specific activity of ²²⁶Ra, ²³²Th and ⁴⁰K natural radionuclides and ¹³⁷Cs anthropogenic radioisotope. The absorbed dose rate and the annual effective dose equivalent radiological hazard indices were also estimated. Furthermore, X-ray Fluorescence (XRF) spectrometry measurements were carried out for the quantitative elemental analysis of the sand, in order to investigate any possible chemical pollution by heavy metals. For this aim, different indices such as Enrichment Factor (EF), Geoaccumulation Index (I_geo), Contamination Factor (CF) and Pollution Load Index (PLI) were applied to estimate the level of toxicity imposed on the ecosystem by the detected heavy metals. Finally, in order to identify the crystalline mineral components of the investigated sand samples, X-ray Diffraction (XRD) and Micro-Raman Scattering (MRS) measurements were carried out.

Flour investigation, in terms of physical and chemical pollutants and mineral content, is of great interest, in view of its high consumption for nutritional purposes. In this study, eleven types of flour (five samples for each one), coming from large retailers and employed by people for different cooking food purposes, were investigated through high-purity germanium (HPGe) gamma spectrometry, in order to estimate natural (⁴⁰K) and anthropogenic (¹³⁷Cs) radioisotope specific activity and thus, to assess the radiological risk due to the flour ingestion. Inductively-coupled plasma mass spectrometry (ICP-MS) and inductively-coupled plasma emission spectroscopy (ICP-OES) were also employed to evaluate any possible heavy metal contamination and the mineral composition, and to perform multivariate statistical analysis to deduce the flour authenticity. The evaluation of dose levels due to flour ingestion was performed, for the age category higher than 17 years, taking into account the average yearly consumption in Italy and assuming this need to be satisfied from a single type of flour as a precaution. All obtained results are under the allowable level set by Italian legislation (1 mSv y⁻¹), thus excluding the risk of ionizing radiation effects on humans. As far as heavy metal contamination is concerned, Cd and Pb concentrations turned out to be lower than the threshold values, thus excluding their presence as pollutants. Finally, the multivariate statistical analysis allowed to unambiguously correlate flour samples to their botanical origin, according to their elemental concentrations.

In the present paper, an investigation on the natural and anthropic radioactivity and heavy metals content in a basalt aggregate for concrete from Sicily, Southern Italy, was performed as a case study. In particular, the evaluation of the specific activity of radium-226, thorium-232, potassium-40 and caesium-137 radionuclides was performed by using High-Purity Germanium (HPGe) γ-ray spectrometry, together with the estimation of several indexes developed to evaluate the radiological risk for the population related to radiation exposure, i.e., the alpha index (I_α), the radium equivalent activity (Ra_eq), the absorbed γ-dose rate (D) and the annual effective dose equivalent outdoor (AEDE_out) and indoor (AEDE_in). Moreover, measurements of the average heavy metals (arsenic, cadmium, copper, mercury, nickel, lead, antimony, thallium and zinc) concentrations in the analyzed sample were performed by using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Furthermore, with the aim to investigate any possible chemical pollution, the Enrichment Factor (EF), Geo-accumulation Index (I_geo), Contamination Factor (CF) and Pollution Load Index (PLI) were assessed. Finally, the identification of the source of the aforementioned radioisotopes of natural origin was carried out by X-ray diffraction (XRD), thus identifying the major mineralogical phases present in the investigated basalt aggregate for concrete.

The production chain for game meat is specific and differs from the production chain of meat from domestic livestock. Wild boar meat is a foodstuff consumed in Italy. Wild boars are considered as a reservoir of environmental radionuclides, and the accumulation of radioisotopes can pose a radiological hazard. ⁴⁰K and ¹³⁷Cs activity concentrations were measured through HPGe gamma spectrometry in wild boar meat samples, coming from six hygiene points representative of the entire district of Reggio Calabria, South Italy. Experimental values were found to be in the range of (91 ± 11) Bq kg⁻¹ to (117 ± 14) Bq kg⁻¹ for ⁴⁰K and of (0.09 ± 0.03) Bq kg⁻¹ to (1.61 ± 0.24) Bq kg⁻¹ for ¹³⁷Cs, respectively. Any possible radiological risk for the population was also estimated. Obtained values are in the range of 2.66 µSv a⁻¹ to 4.00 µSv a⁻¹, much lower than the recommended level for the public (1 mSv a⁻¹).

In this article, an investigation of the natural radioactivity content of pyroclastic products from Mt. Etna, eastern Sicily, Southern Italy, was carried out. In particular, the assessment of the average activity concentration of the investigated radionuclides, related to the mineralogical phase composition of the analyzed samples, and the radiological health risk for the population, was performed. High Purity Germanium (HPGe) gamma-ray spectrometry was employed in order to quantify the average specific activity of ²²⁶Ra, ²³²Th, and ⁴⁰K natural radioisotopes. The absorbed gamma dose rate (D), the radium equivalent activity (Ra_eq), the hazard indices (H_in and H_ex), the annual effective dose equivalent outdoor (AEDE_out), and the excess lifetime cancer risk (ELCR) were also estimated in order to assess any possible radiological hazard for the population. In our case, they were found to be lower than the maximum recommended values for the population members, thus reasonably excluding radiological hazard effects. Moreover, the identification of the source of the aforementioned naturally occurring radionuclides was attempted by X-ray Diffraction (XRD) and Micro-Raman Scattering (MRS), thereby recognizing the main radioisotope-bearing minerals present in the investigated pyroclastic products. Finally, Pearson correlation, Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA) were performed by processing observed radioactivity and radiological parameters in order to determine their correlation with the sampling locations.