In the present research, the properties of ultraviolet (UV) visible (daylight invisible) fluorescent coatings modified by the addition of SiO₂ and TiO₂ nanoparticles were studied. Structural, surface, and mechanical properties and changes in the coatings caused by accelerated ageing were analyzed. The results showed that the addition of nanoparticles caused the changes in unaged and aged printed coatings. Reflectance measurements of modified coatings showed that addition of TiO₂ nanoparticles improved the visual effect of the unaged coatings. Furthermore, results have shown that the addition of SiO₂ did not diminish the reflectance of the modified coatings after ageing. The results of roughness measurements showed that the addition of SiO₂ decreased roughness after the ageing process, probably due to the degradation process indicated by Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR) spectroscopy. The roughness of the coatings with TiO₂ nanoparticles was increased after the ageing on the samples with higher concentrations of TiO₂ due to the agglomerates of plastisol formed on the surface of the coatings, visible in SEM images. Surface analysis of coatings showed that TiO₂ caused an increase in the polarity of the surface coatings. Results of the bending stiffness showed that the addition of the nanoparticles to the coating, especially of SiO₂, significantly improved the bending stiffness of the unaged samples.

In this study, the mechanical and thermal properties of poly(lactic acid) (PLA) blends with an addition of poly(ε–caprolactone) (PCL) and fumed silica (SiO₂) were evaluated to research the possibility of their use as relief printing plates for embossing processes. PCL and nano-silica were added to the PLA matrix at different concentrations. Morphological, thermal and mechanical analyses were performed to determine the properties and possible functional characteristics of the studied blends. SEM micrographs showed that unmodified PLA/PCL blends exhibit a morphology typical of incompatible blends with clearly visible spherical domains of dispersed PCL in PLA. In particular, the results of the hardness tests showed that the selected blends have the optimal hardness (between 65 SH D and 75 SH D) for use in the embossing process. The tensile tests showed that the addition of nano-silica to neat PLA and to the PLA/PCL blends 50/50 and 60/40 improved the mechanical properties of the blends, especially stiffness and toughness. The DMA results showed that the addition of smaller amounts of SiO₂ can contribute to an increase in storage modulus, which is due to good dispersion and distribution of SiO₂ in the matrix. DSC analysis showed that the addition of PCL to PLA polymer increased the thermal stability of PLA and that the addition of nano-silica increased the degree of crystallinity of PLA. The TGA results showed that the addition of nano-silica improved the thermal degradation behavior of the studied blends, especially for blends modified with 3 wt% nano-silica. The results show that it is possible to optimize the mechanical and thermal properties of the blends with the aim of using them in the embossing process.

In this research a biodegradable blend of poly(ɛ-caprolactone) (PCL) and poly(lactic acid) (PLA) is proposed as a new material for the production of a relief printing plate used for special applications on packaging materials, i.e., the embossing process. Coconut fibers (CFs) were added as a natural filler to PCL/PLA blends to improve the functional properties of the prepared blends. Thermal, mechanical and surface analyses were performed on the unaged and artificially aged blends. The results showed that CF has been proven to optimize the hardness of the blend, which is crucial for the production of relief plate for embossing applications. The lowest hardness was measured on neat PCL (53.30° Sh D) and the highest value on PCL/PLA/CF 70/30/3.0 blend (60.13° Sh D). Stronger interfacial interactions were present at the PLA/CF interface because the interfacial free energy is closer to zero and the work of adhesion and spreading coefficient are higher than for the PCL/CF interface. The results of thermal analysis of unaged and aged blends showed that ageing for 3 weeks resulted in significantly lower thermal stability, especially for neat PCL and PCL/PLA 80/20 blends. Blends with a higher content of PLA and CF showed a slightly increased ageing resistance, which is attributed to the increased crystallinity of PLA after ageing due to the addition of CF showed in the DSC diagrams.

Starch-based pH-sensing films with bacterial nanocellulose (BNC) and red cabbage anthocyanins (RCA) as active components were investigated in this research. Their structural, physical, surface and colorimetric properties were analyzed, mainly as a function of BNC concentration. The aim of the research was to relate the changes in the intermolecular interactions between the components of the films (starch, anthocyanins and BNC) to the physical, surface and colorimetric properties that are important for the primary intended application of the produced films as pH indicators in smart packaging. The results showed that maize starch (MS) was more suitable as a matrix for the stabilization of anthocyanins compared to potato starch (PS). PS-based films showed a lower value of water contact angle than MS-based films, indicating stronger hydrophilicity. The swelling behavior results indicate that the concentrations of BNC in MS-based films (cca 10%) and the concentration of about 50% BNC in PS-based films are required if satisfactory properties of the indicator in terms of stability in a wet environment are to be achieved. The surface free energy results of PS-based films with BNC were between 62 and 68 mJ/m² and with BNC and RCA between 64 and 68 mJ/m²; for MS-based films, the value was about 65 mJ/m² for all samples with BNC and about 68 mJ/m² for all samples with BNC and RCA. The visual color changes after immersion in different buffer solutions (pH 2.0–10.5) showed a gradual transition from red/pink to purple, blue and green for the observed samples. Films immersed in different buffers showed lower values of 2 to 10 lightness points (CIE L*) for PS-based films and 10 to 30 lightness points for MS-based films after the addition of BNC. The results of this research can make an important contribution to defining the influence of intermolecular interactions and structural changes on the physical, surface and colorimetric properties of bio-based pH indicators used in smart packaging applications.

The aim of this research was to analyze the influence of the solvents commonly used in flexography on photopolymer and ethylene propylene diene monomer (EPDM) flexographic printing plates and prints. EPDM plates are recommended when the reproduction process includes a higher amount of the solvents or aggressive solvents. Since additional UV treatment of flexographic printing plates could decrease the interaction between the plate and solvent, photopolymer and EPDM plates were treated with varied UV radiation and exposed to different types of solvents. Effects of the UV treatment and of the solvents on printing plate properties and on prints were analyzed. Results show that EPDM plates are more resistant to solvents in terms of the degree of swelling; however, surface properties of the plates were affected for both plate materials. In addition, the degree of swelling and increased hardness due to UV radiation were crucial for changes of the width of printed lines, and altered surface free energy affected the thickness of deposited ink film for both plate materials. Therefore, depending on the qualitative requirements of specific printed film, the duration of UV treatment can be adjusted for use with specific types of printing plate and solvent.

In this research, eco-friendly PLA filaments were 3D-printed using FDM. Three geometric shapes with different orders of rotational symmetry were selected to create infill patterns: an equilateral triangle, a square, and a regular hexagon. Additionally, each of these three infill patterns was modified by rotating the basic shape used to form the infill pattern by 0°, 15°, and 30°. The objective of this study was to analyze how the order of rotational symmetry within the infill pattern affects the mechanical properties of the printed specimens. To ensure consistency, infill density was kept as uniform as possible across all samples produced. DMA and tensile tests were performed on the produced specimens. The obtained mean values in the tensile measurements were compared using the Kruskal–Wallis test. Dunn’s test was used for post hoc pairwise multiple comparisons. DMA showed that when comparing different infill patterns, the specimens with an order of rotational symmetry of 3 (triangle) showed the highest modulus of elasticity, and the specimens with a 15° rotation regardless of shape generally had the highest storage modulus. Statistical analysis showed that the maximum force of the infill pattern with an order of rotational symmetry of 3 (triangle) was the least affected by the rotation angle, while the infill pattern with an order of rotational symmetry of 4 (square) and a 0° rotation displayed a significantly higher value of the maximum force than other patterns. The infill pattern with an order of rotational symmetry of 6 (hexagon) was moderately affected by the angle of rotation. Given the numerous infill patterns utilized in FDM, the results of this research offered a new viewpoint and insights into optimizing the mechanical properties of 3D-printed infill patterns.