Bulk Mo ₂ S ₃ may be dispersed into colloidal nanosheets and assembled into thin films with potential for use in gas sensors.

The extensive family of transition metal chalcogenides has been comprehensively investigated owing to their diverse useful properties. However, even among them, there are ones that have received comparatively less attention; in particular, these are molybdenum and niobium sulfides and selenides with the composition of M : Q = 2 : 3 (M = Mo, Nb; Q = S, Se). Mo or Nb chalcogenides with this stoichiometry may adopt one of two structures: (i) sesquichalcogenides M₂Q₃, where important structural elements are infinite metal chains, or (ii) self-intercalated compounds M_1.33Q₂, in which extra M atoms are inserted between MQ₂ layers. Depending on the M–Q combination, in practice, either none, one, or both of them may exist. The reasons for chemical dissimilarity in the series of seemingly related compounds haven’t been addressed until the present work. Here, we present the first generalized comparative study of these chalcogenides by quantum-chemical computations verified by laboratory experiments. High-temperature phases of Mo₂S₃ and Nb₂Se₃ may be stably isolated at room temperature, while “Nb₂S₃” and “Mo₂Se₃” had not been obtained, nor were they expected to exist from DFT data. The structure-determining motifs of sesquichalcogenides M₂Q₃ are metallic chains, and thus, apparently, if metal's electron deficiency (or excess) prevents the formation of M–M chains, then the M₂Q₃-type structure cannot form. If the metal has an adequate electron density and the structure does form at high temperature (as it happens for Mo₂S₃ and Nb₂Se₃), then it can be kinetically stabilized by quenching, and stored under laboratory conditions for long times. However, if Nb₂Se₃ is left to cool down slowly, it undergoes phase transition to iso-stoichiometric intercalate Nb_1.333Se₂, in good agreement with DFT predictions of the close values of their free energies. Isostructural intercalate Nb_1.333S₂ is found to be the only experimental product in the Nb–S system, in full accordance with DFT prediction. Effective stabilization of self-intercalated phases is provided by significant charge transfer from intercalated Nb atoms to the NbQ₂ layers, as confirmed by DFT. The obtained data may serve to get insight into polymorphism of some less-studied transition metal chalcogenides and to promote their use for future functional materials.

The family of chalcogenide molybdenum clusters is well presented in the literature by a series of compounds of nuclearity ranging from binuclear to multinuclear articulating octahedral fragments. Clusters actively studied in the last decades were shown to be promising as components of superconducting, magnetic, and catalytic systems. Here, we report the synthesis and detailed characterization of new and unusual representatives of chalcogenide clusters: square pyramidal complexes [{Mo₅(μ₃-Se)ⁱ₄(μ₄-Se)ⁱ(μ-pz)ⁱ₄}(pzH)^t₅]^1+/2+ (pzH = pyrazole, i = inner, t = terminal). Individually obtained oxidized (2+) and reduced (1+) forms have very close geometry (proven by single-crystal X-ray diffraction analysis) and are able to reversibly transform into each other, which was confirmed by cyclic voltammetry. Comprehensive characterization of the complexes, both in solid and in solution, confirms the different charge state of molybdenum in clusters (XPS), magnetic properties (EPR), and so on. DFT calculations complement the diverse study of new complexes, expanding the chemistry of molybdenum chalcogenide clusters.