The continuous energy-harvesting in moisture environment is attractive for the development of clean energy source. Controlling the transport of ionized mobile charge in intelligent nanoporous membrane systems is a promising strategy to develop the moisture-enabled electric generator. However, existing designs still suffer from low output power density. Moreover, these devices can only produce short-term (mostly a few seconds or a few hours, rarely for a few days) voltage and current output in the ambient environment. Here, we show an ionic diode–type hybrid membrane capable of continuously generating energy in the ambient environment. The built-in electric field of the nanofluidic diode-type PN junction helps the selective ions separation and the steady-state one-way ion charge transfer. This directional ion migration is further converted to electron transportation at the surface of electrodes via oxidation-reduction reaction and charge adsorption, thus resulting in a continuous voltage and current with high energy conversion efficiency.

We investigate the dependence of friction forces on normal load in incommensurate micrometer-size contacts between atomically smooth single-crystal graphite surfaces under ambient conditions. Our experimental results show that these contacts exhibit superlubricity (superlow friction), which is robust against the application of normal load. The measured friction coefficients are essentially zero and independent of the external normal load up to the maximum pressure of our experiment, 1.67 MPa. The observation of load-independent superlubricity in microscale contacts is a promising result for numerous practical applications.

Harvesting the energy from the interaction between hygroscopic materials and atmospheric water can generate green and clean energy. However, the ion diffusion process of moisture-induced dissociation leads to the disappearance of the ion concentration gradient gradually, and there is still a lack of moisture-based power generation devices with truly continuous operation, especially the duration of the current output still needs to be extended. Here, we propose a design for reconstructing the ion concentration gradient by coupling photocatalytic hydrogen evolution reaction with hydrovoltaic effect, to report a moisture-enabled electric generator (MEG) with continuous current output. We show that the introduction of the photocatalytic layer not only absorbs light energy to greatly increase the power generation of the MEG (500% power density enhancement), but more importantly, the photocatalytic hydrogen evolution process consumes the pre-stacked ions to restore the ion concentration gradient, allowing the MEG to continuously output current for more than 600 hours, which is 1 to 2 orders of magnitude higher than the great majority of existed MEGs in terms of the current output duration.

To date, structural superlubricity in microscale contacts is mostly observed in intrinsic graphite flakes that are cleaved by shearing from HOPG mesas in situ or friction pairs assembled in vacuum due to the high requirement of ultra clean interface for superlubricity, which severely limits their practical applications. Herein, we report observations on microscale structural superlubricity in graphite flake pairs assembled under ambient conditions, where contaminants are inevitably present at the interfaces. For such friction pairs, we find a novel running-in phenomenon, where the friction decreases with reciprocating motions, but no morphological or chemical changes can be observed. The underlying mechanism for the new running-in process is revealed to be the removal of third bodies confined between the surfaces. Our results improve the understanding of microscale superlubricity and may help extend the practical applications of superlubricity.