Machine-tool life is one limiting factor affecting productivity. The requirement for wear-resistant materials for cutting tools to increase their longevity is therefore critical. Titanium diboride (TiB₂) coated cutting tools have been successfully employed for machining of AlSi alloys widely used in the automotive industry. This paper presents a methodological approach to improving the self-lubricating properties within the cutting zone of a tungsten carbide milling insert precoated with TiB₂, thereby increasing the operational life of the tool. A unique hybrid Physical Vapor Deposition (PVD) system was used in this study, allowing diamond-like carbon (DLC) to be deposited by filtered cathodic vacuum arc (FCVA) while PVD magnetron sputtering was employed to deposit WS₂. A series of ~100-nm monolayer DLC coatings were prepared at a negative bias voltage ranging between −50 and −200 V, along with multilayered DLC-WS₂ coatings (total thickness ~500 nm) with varying number of layers (two to 24 in total). The wear rate of the coated milling inserts was investigated by measuring the flank wear during face milling of an Al-10Si. It was ascertained that employing monolayer DLC coating reduced the coated tool wear rate by ~85% compared to a TiB₂ benchmark. Combining DLC with WS₂ as a multilayered coating further improved tool life. The best tribological properties were found for a two-layer DLC-WS₂ coating which decreased wear rate by ~75% compared to TiB₂, with a measured coefficient of friction of 0.05.

In this study, the effect of increasing aluminum content and magnetic steering field strength on the structure and wear behavior of arc PVD AlTiN coatings is discussed. Deposition was done by means of an industrial-scale PVD unit for tool coating. The aluminium content in the AlTi source material was increased from 67 to 73 at.%. We applied two settings of the magnetic field that steers the arc across the cathode surface thereby evaporating the AlTi alloy differently. The resulting coating thickness ranged from 3.5 to about 7 µm. Cemented tungsten carbide was used as substrate material. Coating properties like hardness, adhesion, and crystal phases were analyzed by indentation and X-ray diffraction, respectively. The wear behaviour of the different AlTiN hard coatings were investigated in two ways. In a first idealized test, cyclic impacting was done applying a constant force. The resulting wear pattern was quantified by an Alicona multi-focus microscope. A second wear test was done by metal cutting under realistic conditions. Fly milling of ductile cast iron (EN-GJS-700) was performed with regular interruptions in order to measure the increasing wear mark. As expected, aluminium contents above 67 at.% (in the metal fraction of the coating) lead to a decreased wear resistance as the soft hexagonal phase exceeds values of a few vol.%. However, it was found that the formation of the hexagonal phase can be effectively influenced and delayed by increasing the magnetic steering field at the cathode. The wear behavior observed in cyclic impact testing corresponds well to results obtained with the more complex loading situation encountered in milling.

The conventional cutting tools used for machining titanium alloys normally experience rapid tool wear, and it is generally difficult to achieve a cutting speed over 60 m/min. In this paper, a comprehensive study on improving the machining of Ti-6Al-4V alloy is presented, focusing on high-speed end milling at 100 m/min. Three different AlCrN PVD-coated cemented carbide tools were employed over cemented solid carbide endmills. The study aimed to understand the factors influencing tool performance and, particularly, the uncommon tool wear behavior characterized by chipping on the rake face. The research methodology involves a detailed investigation of coating properties, mechanical characteristics, surface defects, and tool edge geometries. Mechanical properties were measured to assess the resistance to plastic deformation and impact fatigue fracture resistance. Surface defects were meticulously observed, and tool edge geometries were evaluated through optical microscopies. These analyses uncover the key factors contributing to the best tool performance, notably the resistance to plastic deformation (H³/E² ratio), impact fatigue fracture resistance, and maintaining uniform tool edge geometries. The results of this study reveal that the moderate stress C3 coating outperformed the other two coatings, exhibiting a 1.5-times-longer tool life, a relatively stable cutting force curve, and favorable friction conditions in the cutting zone.

The machining of austenitic stainless steel alloys is usually characterized by high levels of adhesion and built-up edge; therefore, improving tribological conditions is fundamental to obtaining higher tool life and better surface finish. In this work, three different Al_0.6Ti_0.4N coatings are compared, two deposited by Cathodic Arc Evaporation (CAE) and one with High-Power Impulse Magnetron Sputtering (HiPIMS). The effects of the micromechanical properties and the microstructure of the coatings were then studied and related to the machining performance. Both arc-deposited coatings (CAE 1 and 2) exhibited similar average tool life, 127 min and 128 min, respectively. Whereas the HiPIMS lasted for only 21.2 min, the HiPIMS-coated tool had a much shorter tool life (more than six times lower than both CAE coatings) due to the intense adhesion that occurred in the early stages of the tool life. This higher adhesion ultimately caused built-up edge and chipping of the tool. This was confirmed by the cutting forces and more deformation on the shear band and undersurface of the chips, which are related to higher levels of friction. The higher adhesion could be attributed to the columnar structure of the HiPIMS and the (111) main texture, which presents a higher surface energy when compared to the dominant (200) from both arc depositions. Studies focused on tribology are necessary to further understand this relationship. In terms of micromechanical properties, tools with the highest plasticity index performed better (CAE 2 = 0.544, CAE 1 = 0.532, and HiPIMS = 0.459). For interrupted cutting machining where adhesion is the main wear mechanism, a reserve of plasticity is beneficial to dissipate the energy generated during friction, even if this was related to lower hardness levels (CAE 2 = 26.6 GPa, CAE 1 = 29.9 GPa, and HiPIMS = 33.6 GPa), as the main wear mechanism was adhesive and not abrasive.

TiB₂ is well established as a superhard coating with a high melting point and a low coefficient of friction. The brittle nature of borides means they cannot be utilised with arc evaporation, which is commonly used for the synthesis of hard coatings as it provides a high deposition rate, fully ionised plasma and good adhesion. In this work, TiB₂ conical cathodes with non-standard sintering additives (carbon and TiSi₂) were produced, and the properties of the base material, such as grain structure, hardness, electrical resistivity and composition, were compared to those of monolithic TiB₂. The dependence of the produced cathodes’ electrical resistivity on temperature was evaluated in a furnace with an argon atmosphere. Their arc–evaporation suitability was assessed in terms of arc mobility and stability by visual inspection and by measurements of plasma electrical potential. In addition, shaping the cathode into a cone allowed investigation of the influence of an axial magnetic field on the arc spot. The produced cathodes have a bulk hardness of 23–24 GPa. It has been found that adding 1 wt% of C ensured exceptional arc-spot stability and mobility, and requires lower arc current compared to monolithic TiB₂. However, poor cathode utilization has been achieved due to the steady generation of cathode flakes. The TiB₂ cathode containing 5 wt% of TiSi₂ provided the best balance between arc-spot behaviour and cathode utilisation. Preventing cathode overheating has been identified as a main factor to allow high deposition rate (±1.2 µm/h) from TiB₂-C and TiB₂-TiSi₂ cathodes.

Combinatorial deposition, comprising filtered cathodic vacuum arc (FCVA) and physical vapor deposition (PVD) magnetron sputtering is employed to deposit molybdenum disulphide (MoS₂) and titanium (Ti) thin films onto TiB₂-coated tool inserts specifically designed for the dry machining of aluminium alloys. Titanium is deposited by FCVA while MoS₂ is magnetron sputtered. The deposition set up allows several compositions of Ti-MoS₂ to be deposited simultaneously, with Ti content ranging between 5 and 96 at. %, and their machining performances to be evaluated. Milling took place using a CNC Vertical Machining Center at a 877 mm/min feed rate. The effect of different coating compositional ratios on the degree of aluminium sticking when a milling insert is used to face mill an Al alloy (SAE 6061) was investigated using a combination of energy-dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) analysis. XPS studies suggest that the greater degree of Al sticking on the rake face of the inserts is due to the formation of greater amounts of non-protective Ti-O phases. EDX mapping of the milling inserts after machining reveal that a Ti:MoS₂ ratio of around 0.39 prevents Al from sticking to the tool edges. Since we prevent Al from sticking to the tool surface, the resultant machined surface finish is improved thus validating the machining performance of TiB₂-coated tools using optimum compositions of Ti:MoS₂ thin film coatings.