A common sustainability issue, arising in production systems, is the efficient use of resources for providing goods or services. With the increased interest in a hydrogen (H₂) economy, the life-cycle environmental performance of H₂ production has special significance for assisting in identifying opportunities to improve environmental performance and to guide challenging decisions and select between technology paths. Life cycle impact assessment methods are rapidly evolving to analyze multiple environmental impacts of the production of products or processes. This study marks the first step in developing process-based streamlined life cycle analysis (LCA) of several H₂ production pathways combining life cycle impacts at the midpoint (17 problem-oriented) and endpoint (3 damage-oriented) levels using the state-of-the-art impact assessment method ReCiPe 2016. Steam reforming of natural gas, coal gasification, water electrolysis via proton exchange membrane fuel cell (PEM), solid oxide electrolyzer cell (SOEC), biomass gasification and reforming, and dark fermentation of lignocellulosic biomass were analyzed. An innovative aspect is developed in this study is an analysis of water consumption associated with H₂ production pathways by life-cycle stage to provide a better understanding of the life cycle water-related impacts on human health and natural environment. For water-related scope, Water scarcity footprint (WSF) quantified using Available WAter REmaining (AWARE) method was applied as a stand-alone indicator. The paper discusses the strengths and weaknesses of each production pathway, identify the drivers of environmental impact, quantify midpoint environmental impact and its influence on the endpoint environmental performance. The findings of this study could serve as a useful theoretical reference and practical basis to decision-makers of potential environmental impacts of H₂ production systems.

Olive cultivation is expanding rapidly in the northwestern part of Greece, under both rainfed and irrigated practices. Irrigation can result in larger yields and economic returns, but trade-offs in the water–energy–pollution nexus remain a controversial and challenging issue. This study presents an environmental Life Cycle Assessment (LCA) of Greek olive orchard systems in the plain of Arta (Epirus), comparing rainfed (baseline), Decision Support System (DSS)-based (smart) irrigation practices and farmer experience-based (conventional) irrigation practices. The contributions in this paper are, first, to provide a first quantitative indication of the environmental performance of Greek olive growing systems under different management strategies, and second, to detail the advantages that can be achieved using smart irrigation in olive cultivation in the Greek and Mediterranean contexts. Eighteen midpoints (e.g., climate change, water scarcity, acidification, freshwater eutrophication, etc.), two endpoints (damages on human health and ecosystem quality), and a single score (overall environmental impact) were quantified using the IMPACT World+ life cycle impact assessment method. The LCA model was set up using the OpenLCA software v1.10.3. The functional units were 1 ton of product (mass-based) and 1 ha of cultivated area (area-based) on a cradle-to-farm gate perspective. Irrigated systems had the lowest impacts per mass unit due to higher yields, but showed the highest impacts per cultivated area. The DSS-based irrigation management could reduce water and energy use by 42.1% compared to conventional practices. This is translated into a reduction of 5.3% per 1 ton and 10.4% per 1 ha of the total environmental impact. A sensitivity analysis of impact assessment models demonstrated that the benefits could be up to 18% for 1 ton of product or 22.6% for 1 ha of cultivated land. These results outline that DSS-based irrigation is a promising option to support less resource-intensive and sustainable intensification of irrigated agriculture systems in the plain of Arta.