Production of synthetic diesel fuel by the Fischer–Tropsch (FT) method in the presence of a composite catalyst prepared by mechanically mixing 35 wt % Co/SiO2, 30 wt % HZSM-5, and 30 wt % Al2O3has...
The effects of the H2/CO ratio, pressure, temperature, and the reaction-gas recycle ratio on the selectivity for hydrocarbons (HCs), including long-chain C35+ HCs, in the Fischer–Tropsch synthesis ove
The study investigates the effects of nickel introduction methods on the properties of a hybrid cobalt catalyst in a combination of Fischer–Tropsch synthesis and the hydroprocessing of the synthesized products. At 240°C, 2 MPa, and syngas WHSV 1000 h –1 , the catalytic performances were compared, the products were analyzed for the hydrocarbon and fractional compositions, and the characteristics of the synthesized fuels were determined. Among the catalysts differing in nickel introduction method, the sample with a nickel-containing zeolite component prepared by ion exchange was found to have the highest hydrogenation activity, while the sample with a metal component generated by joint cobalt/nickel introduction [Co/SiO 2 + Ni(i)/HZSM-5 + Al 2 O 3 ] exhibited the highest isomerization activity.
Crosslinked polyethylene (XLPE) has been the cornerstone material in the power industry for insulating high-voltage cables due to its exceptional properties, including reduced dielectric loss, high dielectric constant and thermal conductivity, and excellent resistance to electrical stress. In the current study, in order to further enhance the electrical and mechanical properties of XLPE’s various types of nanofillers such as metal oxides, boron nitride nanosheets of nanosilica and graphene oxide are incorporated into the XLPE matrix. These nanoparticles promote the occurrence of numerous trap sites, even at modest concentrations, due to their extensive interfacial regions, which affect crucial characteristics including breakdown voltage strength, electrical tree growth, structural defects, space charge accumulation, and thermal aging. The present review summarizes the effects of nanoparticles on the dielectric performance of XLPE. At the same time, the current advancements in the development of a new generation of recyclable insulation materials are briefly discussed.
This study investigates the production of diesel fuels by integrated Fischer–Tropsch synthesis over a bifunctional cobalt catalyst consisting of a cobalt component (Co–Al 2 O 3 /SiO 2 ) and a zeolite-containing component (ZSM-5). The catalytic properties were tested in a continuous-flow reactor with a stationary catalyst bed at 240–250°C, 2 MPa, and gas WHSV 1000 h –1 . The effects of the SiO 2 /Al 2 O 3 ratio in a HZSM-5 zeolite on the catalytic performance, catalyst deactivation rate, and hydrocarbon and fractional compositions of the synthetic product were identified. The low-temperature properties of the synthesized diesel fuel satisfy the current requirements for winter fuels.