Since April 2004, preparatory work prior to CO2 injection has been conducted in the CO2SINK Project, the European Union's first research and development activity on the in-situ testing of geological storage of CO2 near the town of Ketzin, Germany. Carbon dioxide will be injected into a saline aquifer of the Triassic Stuttgart Formation in an anticlinal structure of the northeast German Basin. The drilling of one injection and two observation wells will commence at the end of 2006. The predrilling phase focuses on the baseline geological parameters of the anticline. The Stuttgart Formation is lithologically heterogeneous; it consists of sandy channel-(string)-facies rocks, with good reservoir properties alternating with muddy flood-plain-facies rocks of poor reservoir quality. Playa-type rocks form the immediate cap rock above the CO2SINK reservoir. A geostatistical approach has been applied to describe the reservoir architecture between and beyond well control. This model forms the basis for the generation of reservoir-dynamic models of CO2 injection that assist in the planning of injection operations and in the understanding of CO2 plume evolution. A verification of the geometry of the reservoir and the structural situation of its overburden is expected from a three-dimensional baseline seismic survey that was conducted in the autumn of 2005. Laboratory experiments under simulated in-situ conditions were performed to evaluate the geophysical signature of rocks saturated with CO2. The chemical composition of the groundwater and the CO2 flux in the soil were analyzed across the Ketzin anticline, providing the baseline for a monitoring program during and after injection of CO2, targeted at the detection of potential CO2 leakage from the storage reservoir.

The Ketzin pilot site, led by the GFZ German Research Centre for Geosciences, is Europe’s longest-operating on-shore CO₂ storage site with the aim of increasing the understanding of geological storage of CO₂ in saline aquifers. Located near Berlin, the Ketzin pilot site is an in situ laboratory for CO₂ storage in an anticlinal structure in the Northeast German Basin. Starting research within the framework of the EU project CO₂SINK in 2004, Ketzin is Germany’s first CO₂ storage site and fully in use since the injection began in June 2008. After 39 months of operation, about 53,000 tonnes of CO₂ have been stored in 630–650 m deep sandstone units of the Upper Triassic Stuttgart Formation. An extensive monitoring program integrates geological, geophysical and geochemical investigations at Ketzin for a comprehensive characterization of the reservoir and the CO₂ migration at various scales. Integrating a unique field and laboratory data set, both static geological modeling and dynamic simulations are regularly updated. The Ketzin project successfully demonstrates CO₂ storage in a saline aquifer on a research scale. The results of monitoring and modeling can be summarized as follows: (1) Since the start of the CO₂ injection in June 2008, the operation has been running reliably and safely. (2) Downhole pressure data prove correlation between the injection rate and the reservoir pressure and indicates the presence of an overall dynamic equilibrium within the reservoir. (3) The extensive geochemical and geophysical monitoring program is capable of detecting CO₂ on different scales and gives no indication for any leakage. (4) Numerical simulations (history matching) are in good agreement with the monitoring results.

A 3D 25-fold seismic survey with a bin size of 12 by 12m and about 12km2 of subsurface coverage was acquired in 2005 near a former natural gas storage site west of Berlin, as part of the five-year EU funded CO2SINK project. Main objectives of the seismic survey were to verify earlier geologic interpretations of structure based on vintage 2D seismic and borehole data and to map, if possible, the reservoir pathways in which the CO2 will be injected at 650m depth, as well as providing a baseline for future seismic surveys and planning of drilling operations. The uppermost 1000m are well imaged and show an anticlinal structure with an east-west striking central graben on its top that extendsdown to the target horizon. About 30m of throwis seen on the bounding faults. No faults are imaged near the planned drill sites. Remnant gas, cushion and residual gas, is present near the top of the anticline in the depth interval of about 250–400m and has a clear seismic signature; both higher amplitudes in the reservoir horizons and velocity pulldown are observed. Amplitude mapping of these remnant gas horizons shows that they do not extend as far south as the injection site, which is located on the southern flank of the anticline. Amplitude anomalies, gas chimneys along an east-west striking fault, show that the stored or remnant gas either has been or is presently migrating out of the reservoir formations. Summed amplitude mapping of the planned injection horizon indicates that this lithologically heterogeneous formation may be more porous at the injection site.

At Ketzin, located west of Berlin, the GFZ German Research Centre for Geosciences operates Europe's longest- running on-shore CO2 storage site. The Ketzin pilot site has been developed since 2004 and comprises three wells to depths of 750 m to 800 m and one shallow observation well, an injection facility and permanently installed monitoring devices. Since June 2008, CO2 is injected into 630 m to 650 m deep sandstone units (Upper Triassic Stuttgart Formation) in an anticlinal structure of the Northeast German Basin. Until mid of May 2012, about 61,400 t of CO2 have been stored safely. One of the most comprehensive monitoring concepts worldwide is applied and capable of detecting the behaviour of the CO2 in the subsurface. The Ketzin project demonstrates safe CO2 storage in a saline aquifer on a research scale and effective monitoring. This paper summarizes the key results obtained after four years of CO2 injection