Cellular automata models have emerged as a valuable tool in corrosion management. This manuscript provides an overview of the application of cellular automata models in corrosion research, highlighting their benefits and contributions to understanding the complex nature of corrosion processes. Cellular automata models offer a computational approach to simulating corrosion behavior at the microscale, capturing the intricate interactions between electrochemical reactions, material properties, and environmental factors and generating a new vision of predictive maintenance. It reviews the key features of cellular automata, such as the grid-based representation of the material surface, the definition of state variables, and the rules governing cell-state transitions. The ability to model local interactions and emergent global behavior makes cellular automata particularly suitable for simulating corrosion processes. Finally, cellular automata models offer a powerful and versatile approach to studying corrosion processes, expanding models that can continue to enhance our understanding of corrosion and contribute to the development of effective corrosion prevention and control strategies.
1 October 2021 in Solar Energy Materials and Solar Cells
Solar thermal plants typically undergo trough operational cycles spanning between 20 and 25 years, highlighting the critical need for accurate assessments of long-term component evolution. Among these components, the heat storage media (molten salt) is crucial in plant design, as it significantly influences both the thermophysical properties of the working fluid and the corrosion of the steel components in thermal storage systems. Our research focused on evaluating the long-term effects of operating a low-melting-point ternary mixture consisting of 30 wt% LiNO3, 57 wt% KNO3, and 13 wt% NaNO3. The ternary mixture exhibited a melting point of 129 °C and thermal stability above 550 °C. Over 15,000 h, the heat capacity decreased from 1.794 to 1.409 J/g °C. Additionally, saline components such as CaCO3 and MgCO3, as well as lithium oxides (LiO and LiO2), were detected due to the separation of the ternary mixture. A 30,000 h exposure resulted in the formation of Fe2O3 and the presence of Cl, indicating prolonged interaction with the marine environment. This investigation highlights the necessity of analyzing properties under actual operating conditions to accurately predict the lifespan and select the appropriate materials for molten salt-based thermal storage systems.
Cellular automata (CA) models have emerged as a valuable tool in corrosion management. This manuscript provides an overview of the application of cellular automata models in corrosion research, highlighting their benefits and contributions to understanding the complex nature of corrosion processes. Cellular automata models offer a computational approach to simulate corrosion behavior at the microscale, capturing the intricate interactions between electrochemical reactions, material properties, and environmental factors generating a new vision of predictive maintenance. It discusses the key features of cellular automata, such as the grid-based representation of the material surface, the definition of state variables, and the rules governing cell-state transitions. The ability to model local interactions and emergent global behavior makes cellular automata particularly suitable for simulating corrosion processes. Finally, cellular automata models offer a powerful and versatile approach to studying corrosion processes, expanding models that can continue to enhance our understanding of corrosion and contribute to the development of effective corrosion prevention and control strategies.
There is currently an energy crisis that has led to photovoltaic operators maximizing their resources, making soiling a problem to consider in order to ensure project profitability. Energy production costs are strongly affected by the use of scarcely efficient cleaning techniques that are not suitable for a particular type of contaminant, climate, and installation. This paper introduces a technology that is suitable for studying soiling, thus decreasing the number of variables studied and reliable results were obtained. Our attention is focused on deposited material physicochemistry, local geology, and installation effects. Analysis via scanning electron microscopy and pits revealed a similarity between local geological processes and module soiling, with gypsum being responsible for soil and module cementation. Analysis with Atomic Force Microscopy confirms the cementation effect and crust formation on the lower part of the photovoltaic glass, the latter concentrating in the greatest amount of cemented material. Using a solar simulator, the characteristic curves produced by the cemented material were studied, and it was determined that the lower part of the glass produced the greatest losses (27%). Thus, a non-uniformity deposition was generated, creating resistance between the cells. From the data obtained, it was possible to make recommendations regarding making decisions about plant cleaning, instead of only considering the physicochemical analysis of the deposited material.
The two-tank molten salt thermal storage system is the most common storage solution in concentrated solar power (CSP) plants. Solar salt (60% NaNO3 + 40% KNO3) is the most widely used energy storage material in solar thermal plants. In solar tower technology, where the molten salts must operate at temperatures ranging from 290 °C to 565 °C, several issues related to tank failures have emerged in recent years, with some of these failures attributed to the welding process. The welding process of joints in 316L stainless steel (ASS) probes exposed to a moving flow of a binary mixture containing 60% NaNO3 and 40% KNO3 (solar salt) is analysed. The results were evaluated using scanning electron microscopy (SEM) at 120, 500, 1000, 1500, and 2300 h of exposure. It was identified that arc mechanical oscillations significantly improve the microstructural properties and geometrical characteristics of welded joints, reducing structural defects and improving corrosion resistance. The technique promotes uniform thermal distribution, refined dendrite morphology, and homogeneous alloying element distribution, resulting in lower mass loss in high-temperature molten salt environments. Additionally, oscillation welding optimises the bead geometry, with reduced wetting angles and controlled penetration, making it ideal for high-precision industrial applications and extreme environments, such as molten salt thermal storage systems.