The calcium looping cycle (CaL) possesses outstanding CO₂ capture capacity for future carbon-capturing technologies that utilise CaO sorbents to capture the CO₂ in a looping cycle. However, sorbent degradation and the presence of inert materials stabilise the sorbent, thereby reducing the CO₂ capture capacity. Consequently, the CaO sorbent that has degraded must be replenished, increasing the operational cost for industrial use. CaO sorbents have been modified to enhance their CO₂ capture capacity and stability. However, various CaO sorbents, including limestone, dolomite, biogenesis calcium waste and industrial waste, exhibit distinct behaviour in response to these modifications. Thus, this work comprehensively reviews the CO₂ capture capacity of sorbent improvement based on various CaO sorbents. Furthermore, this study provides an understanding of the effects of CO₂ capture capacity based on the properties of the CaO sorbent. The properties of various CaO sorbents, such as surface area, pore volume, particle size and morphology, are influential in exhibiting high CO₂ capture capacity. This review provides insights into the future development of CaL technology, particularly for carbon-capturing technologies that focus on the modifications of CaO sorbents and the properties that affect the CO₂ capture capacity.

Thick thermal barrier coatings (TBCs) are the main choice in the aviation industry due to their ability to handle elevated temperature exposure in turbines. However, the efficacy of thick TBCs has not been adequate. This study presents a highly durable, thick top-coat (TC) of Lanthanum–gadolinium–yttria stabilized zirconia (La–Gd–YSZ) on high-velocity oxygen fuel (HVOF)-bond coat (HVOF-BC). Crack propagation was quantitatively assessed using a three-dimensional (3D) measuring laser microscope due to higher reliability in calculating the actual crack length of TBC. The findings revealed the HVOF-BC is highly durable with intact structural composition, while the conventional TBC of atmospheric plasma spraying (APS) bond coat (APS-BC) of the same composition and thickness with identical TC was detached at a crack-susceptible zone. The significant enhancement in HVOF-BC is due to the low mixed-oxides growth rate in thermally grown oxide (TGO) with a uniform and dense protective layer of stable Al₂O₃ which reduces crack propagation. Meanwhile, the failure in APS-BC can be attributed to the high TGO growth rate and thickness with segmented and unstable Al₂O₃. Furthermore, detrimental mixed oxides such as spinel Ni(Cr,Al)₂O₄ and NiO lead to disastrous horizontal and compressive cracks. To that end, we study the effect of TGO growth and crack propagation on HVOF-BC TBCs using APS-BC TBCs as a reference.

Hydrogen production is essential in the transition to sustainable energy. This study examines two hydrogen production routes, steam methane reforming (SMR) and chemical looping reforming (CLR), both using raw natural gas as feedstock. SMR, the most commonly used industrial process, involves reacting methane with steam to produce hydrogen, carbon monoxide, and carbon dioxide. In contrast, CLR uses a metal oxide as an oxygen carrier to facilitate hydrogen production without generating additional carbon dioxide. Simulations conducted using Aspen HYSYS analyzed each method’s performance and energy consumption. The results show that SMR achieved 99.98% hydrogen purity, whereas CLR produced 99.97% purity. An energy analysis revealed that CLR requires 31% less energy than SMR, likely due to the absence of low- and high-temperature water–gas shift units. Overall, the findings suggest that CLR offers substantial advantages over SMR, including lower energy consumption and the production of cleaner hydrogen, free from carbon dioxide generated during the water–gas shift process.

Thermal barrier coating (TBC) and cooling air systems are among the technologies that have been introduced and applied in pursuing the extensive development of advanced gas turbine. TBC is used to protect the gas turbine components from the higher operating temperature of advanced gas turbine, whereas cooling air systems are applied to assist TBC in lowering the temperature exposure of protected surfaces. Generally, a gas turbine operates in three main operational modes, which are base load, peak load, and part peak load. TBC performance under these three operational modes has become essential to be studied, as it will provide the gas turbine owners not only with the behaviors and damage mechanism of TBC but also a TBC life prediction in a particular operating condition. For TBC under base load or so called steady-state condition, a number of studies have been reviewed and discussed. However, it has been found that most of the studies have been conducted without the assistance of a cooling air system, which does not simulate the TBC in advanced gas turbine completely. From this review, the studies on TBC-assisted cooling air system to simulate the advanced gas turbine operating conditions have also been summarized, which are limited to test rig simulations under thermal cyclic mode where thermal cyclic represents peak and part peak load conditions. The equipment used to simulate the gas turbine operating condition, test temperatures, and durations are parameters that have been taken into consideration under this review. Finally, a test rig that is capable of simulating both TBC and cooling air effects at a high operating temperature of advanced gas turbines for prolonged exposure under steady-state condition has been proposed to be developed.

Durability of a thermal barrier coating (TBC) depends strongly on the type of mixed oxide in the thermally grown oxide (TGO) of a TBC. This study aims on discovering the effect of thermal stability in the TGO area containing mixed oxides. Two different bondcoats were studied using high-resolution transmission electron microscopy: high-velocity oxygen fuel (HVOF) and air-plasma spray (APS), under isothermal and thermal cyclic tests at 1400 °C. The HVOF bondcoats were intact until 1079 cycles. In comparison, APS failed at the early stage of thermal cycling at 10 cycles. The phase transformation of topcoat from tetragonal to the undesired monoclinic was observed, leading to TBC failure. The results showed that the presence of transient aluminas found in HVOF bondcoat helps in the slow growth of α-Al₂O₃. In contrast, the APS bondcoat does not contain transient aluminas and transforms quickly to α-Al₂O₃ along with spinel and other oxides. This fast growth of mixed oxides causes stress at the interface (topcoat and TGO) and severely affects the TBC durability leading to early failure. Therefore, the mixed oxide with transient aluminas slows down the quick transformation into alpha-aluminas, which provides high thermal stability for a high TBC durability.

Cold spray is a promising approach to repair all damages and defects in aluminum (Al) constituent elements. The study aims to investigate the mechanical and tribological properties of Al coatings deposited using high-pressure cold-spray (HPCS) and low-pressure cold-spray (LPCS) techniques. Al powder was sprayed on a cold-rolled plate of aluminum 1100, which was used as the substrate. The results showed that the micro-hardness of the LPCS Al coating reached up to 196.6 HV before the wear test compared to that of HPCS (174.3 HV). Moreover, more low friction coefficients obtained by LPCS (0.798) than HPCS (0.807) indicated good tribological properties with a high amount of oxide composition. Meanwhile, the wear studies reveal that the specific wear rate of the Al coating of LPCS (0.008) was lower than the HPCS (0.009) as the load increased from 3 N to 5 N, thus providing excellent wear resistance. Therefore, the results exhibited greater mechanical and tribological characteristics for Al coatings produced by the LPCS process than by the HPCS process.