Traditional rejuvenators normally have a great deal of heavy fuel oils to supply the light oil component of asphalt binders, which decreases throughout a long-term aging process. However, heavy fuel oils can easily volatilize at a high recycling temperature (above 180°C), and this leads to a limited portion of reclaimed asphalt pavement (RAP) materials utilized in the recycled asphalt mixture (with a recycling rate less than 30%). Vegetable oils are rich in unsaturated fatty acids, which are similar to the light oil components, and have a better temperature resistance. Therefore, there is potential that vegetable oils can be utilized to recover the aged asphalt binder based on the asphalt rejuvenating mechanism. In this study, two rejuvenators with waste cooking vegetable oils (corn oil and soybean oil) to replace heavy oils and a commercial rejuvenator were used to recover the aged asphalt (extracted from RAP materials) with different ratios (by weight of asphalt) of 2, 4, 6, 8, and 10%. Dynamic shear rheometer (DSR) and rotational viscosity (RV) tests were used to evaluate the physical properties of the recovered asphalt binder. The low-temperature performance of the recovered asphalt binder was also evaluated by the bending beam rheometer (BBR) test. The laboratory tests and statistical analysis of variance (ANOVA) results show that the vegetable oil rejuvenators can effectively decrease the viscosity and stiffness of aged asphalt binder, which is beneficial for both fatigue and low-temperature cracking resistance. Furthermore, the rejuvenator can lower the viscosity and stiffness of the aged asphalt binder with a larger amount of vegetable oil. Overall, the vegetable oil content (6% to 8%) in the rejuvenator is proposed for recovering the aged asphalt binder in consideration of the rutting resistance under high temperatures.

Transforming waste biomass materials into bio-oils in order to partially substitute petroleum asphalt can reduce environmental pollution and fossil energy consumption and has economic benefits. The characteristics of bio-oils and their utilization as additives of asphalts are the focus of this review. First, physicochemical properties of various bio-oils are characterized. Then, conventional, rheological, and chemical properties of bio-oil modified asphalt binders are synthetically reviewed, as well as road performance of bio-oil modified asphalt mixtures. Finally, performance optimization is discussed for bio-asphalt binders and mixtures. This review indicates that bio-oils are highly complex materials that contain various compounds. Moreover, bio-oils are source-depending materials for which its properties vary with different sources. Most bio-oils have a favorable stimulus upon the low temperature performance of asphalt binders and mixtures but exhibit a negative impact on their high-temperature performance. Moreover, a large amount of oxygen element, oxygen-comprising functional groups, and light components in plant-based bio-oils result in higher sensitivity to ageing of bio-oil modified asphalts. In order to increase the performance of bio-asphalts, most research has been limited to adding additive agents to bio-asphalts; therefore, more reasonable optimization methods need to be proposed. Furthermore, upcoming exploration is also needed to identify reasonable evaluation indicators of bio-oils, modification mechanisms of bio-asphalts, and long-term performance tracking in field applications of bio-asphalts during pavement service life.

The purpose of this study is to explore the viscoelastic properties, rutting resistance, and fatigue resistance of waste wood-based biochar-modified asphalt. The biochar with 2%, 4%, and 8% mixing amounts and two kinds of particle size, 75–150 μm and <75 μm, were used as modifiers of petroleum asphalt. Meanwhile, in the control group, a graphite modifier with a particle size of 0–75 μm and mixing amount of 4% was used for comparison. Aged asphalts were obtained in the laboratory by the Rolling Thin Film Oven (RTFO) test and the Pressure Aging Vessel (PAV) test. The viscoelastic properties, rutting resistance, and fatigue resistance of biochar-modified asphalt were evaluated by phase angle, critical high temperature, and fatigue cracking index by the Dynamic Shear Rheometer (DSR) test. In addition, the micromorphology of biochar and graphite was compared and observed by using the scanning electron microscope (SEM). The results show that increasing the mixing amount of biochar gave a higher elastic property and significantly better rutting resistance of the modified asphalt at high temperature. Compared with graphite, the biochar has a rougher surface and more pores, which provides its higher specific surface area. Therefore, it is easier to bond with asphalt to form a skeleton network structure, then forming a more stable biochar–asphalt base structure. In this way, compared to graphite-modified asphalt, biochar-modified asphalt showed better resistance to rutting at high temperature, especially for the asphalt modified with biochar of small particle size. The critical high temperature T^(G*/sinδ) of 4% Gd, 4% WD, and 4% Wd was 0.31 °C, 1.57 °C, and 2.92 °C higher than that of petroleum bitumen. In addition, the biochar asphalt modified with biochar of small particle size had significantly better fatigue cracking resistance than the asphalt modified with biochar of large particle size. The fatigue cracking indexes for 2% Wd, 4% Wd, and 8% Wd were 29.20%, 7.21%, and 37.19% lower by average than those for 2% WD, 4% WD, and 8% WD at 13–37 °C. Therefore, the waste wood biochar could be used as the modifier for petroleum asphalt. After the overall consideration, the biochar-modified asphalt with 2%–4% mixing amount and particle size less than 75 μm was recommended.

The influence of organic additives (Sasobit and RH) and water on the adhesion of the asphalt-aggregate interface was studied according to the surface free energy theory. Two asphalt binders (SK-70 and SK-90), and two aggregate types (limestone and basalt) were used in this study. The sessile drop method was employed to test surface free energy components of asphalt, organic additives and aggregates. The adhesion models of the asphalt-aggregate interface in dry and wet conditions were established, and the adhesion work was calculated subsequently. The energy ratios were built to evaluate the effect of organic additives and water on the adhesiveness of the asphalt-aggregate interface. The results indicate that the addition of organic additives can enhance the adhesion of the asphalt-aggregate interface in dry conditions, because organic additives reduced the surface free energy of asphalt. However, the organic additives have hydrophobic characteristics and are sensitive to water. As a result, the adhesiveness of the asphalt-aggregate interface of the asphalt containing organic additives in wet conditions sharply decreased due to water damage to asphalt and organic additives. Furthermore, the compatibility of asphalt, aggregate with organic additive was noted and discussed.

The warm mix asphalt was fabricated with different moisture contents (0%, 1%, 2%, and 3%) of limestone aggregates using the Superpave gyratory compactor. The moisture susceptibility of asphalt mixtures with an organic wax additive RH was studied. The samples were compacted and tested using the modified Lottman test AASHTO T283, and the X‐ray computed tomography technology was used to capture the internal structure images before and after the freeze‐thaw cycles. The test results show that the air voids were distributed in the size range of 0–5 mm³ and 5–10 mm³. The number of air voids decreased with the increase of air void size and increased after freeze‐thaw cycles. The air void content can be influenced by the residual moisture in aggregates. The higher the moisture content of aggregates is, the larger the air void content is. So, the air void content is likely to be sensitive to moisture damage. The increase ratio of the air void and moisture content of aggregates had good correlation with the indirect tensile strength and tensile strength ratio of the samples. The indirect tensile strength and tensile strength ratio of the samples decreased linearly, and the samples were sensitive to the moisture damage with the increases of increase ratio of the air void/moisture content in aggregates.