Crystalline admixtures (CAs) are new materials for promoting self-healing in concrete materials to repair concrete cracks. They have been applied to tunnel, reservoir dam, road, and bridge projects. The fundamental research and development of CAs are needed concerning their practical engineering applications. This paper reviews the current research progress of commercial CAs, including self-made CA healing cracks; the composition of CA; healing reaction mechanism; the composition of healing products; distribution characteristics of healing products; the influence of service environment and crack characteristics on the healing performance of CA; and coupling healing performance of CA with fiber, expansive agent, and superabsorbent polymers. The current research findings are summarized, and future research recommendations are provided to promote the development of high-performance cement matrix composites.

Based on water penetration in unsaturated concrete of underwater tunnel, a diffusion-advection theoretical model of chloride in undersea concrete tunnel was proposed. The basic parameters including porosity, saturated hydraulic conductivity, chloride diffusion coefficient, initial water saturation, and moisture retention function of concrete specimens with two water-binder ratios were determined through lab-scale experiments. The variation of chloride concentration with pressuring time, location, solution concentration, initial saturation, hydraulic pressure, and water-binder ratio was investigated through chloride transport tests under external water pressure. In addition, the change and distribution of chloride concentration of isothermal horizontal flow were numerically analyzed using TOUGH2 software. The results show that chloride transport in unsaturated concrete under external water pressure is a combined effect of diffusion and advection instead of diffusion. Chloride concentration increased with increasing solution concentration for diffusion and increased with an increase in water pressure and a decrease in initial saturation for advection. The dominant driving force converted with time and saturation. When predicting the service life of undersea concrete tunnel, it is suggested that advection is taken into consideration; otherwise the durability tends to be unsafe.

Manufactured sand, known for its artificial production, eco-friendliness, cost-effectiveness, and sustainability, serves as an excellent alternative to natural sand. Stone powder content plays a crucial role in determining the performance of manufactured sand, significantly enhancing concrete compaction and its ability to withstand environmental degradation. This study aims to explore the feasibility of using environmentally and economically advantageous manufactured sand in the construction of subway tunnel segments in coastal areas. It investigates the impact of stone powder content on the corrosion resistance of concrete made with manufactured sand under the combined influence of chloride salts and stray currents. The analysis covers corrosion tendencies, the post-rusting performance of reinforcement bars, the resistance of concrete to chloride transport, and microstructure properties, which are assessed through electron microscope scanning and mercury compression testing. The findings indicate that the corrosion resistance of manufactured sand concrete generally surpasses that of river sand concrete. Furthermore, stone powder content within the 3–8% range leads to a denser concrete microstructure, reduced porosity, lower free-chloride ion levels, increased polarization resistance of post-corrosion reinforcements, lower corrosion current density, and reduced mass loss of reinforcing bars. This research provides valuable theoretical support for promoting the use of environmentally friendly manufactured sand concrete in subway construction projects.

In order to analyze the process of hydraulic water infiltrating cracked concrete of underwater tunnels, the equation of water transport in unsaturated cracked concrete under pressure was proposed according to the double‐porosity medium model. Penetration tests on prefabricated cracked concrete blocks were conducted, and then the influence of hydraulic pressure, initial saturation, and crack width on water transport was studied. The results show that the larger the water pressure, the lower the initial saturation, and the wider the crack width, then the greater the penetration depth, which can be reasonably explained according to water motion theoretical models in this study. Moreover, the TOUGH2 software was used to simulate the change and distribution of saturation, driving potential, and water velocity of unsaturated cracked concrete, which further proved the experimental results and theoretical analysis. It reflects that both pressure potential and matric potential are the driving force of water transport in underwater cracked concrete, and the driving force will be converted with the change of concrete saturation. In addition, crack width is positively correlated with concrete permeability.

The issue of water seepage poses a significant challenge in tunnel infrastructure. Wet areas are commonly used to evaluate the degree of water seepage in tunnel projects. To investigate the feasibility for numerical simulation to predict a wet area, we selected concrete test blocks with two types of defects—holes and cracks—as the research specimens. Numerical models for various seepage conditions were constructed using TOUGH2, and the results were validated through laboratory experiments. Additionally, the Shenjiamen Subsea Tunnel was simplified into a numerical model, employing TOUGH2 to forecast its future wet area performance within the scope of national standards. The outcomes of our research revealed that point seepage and line seepage exhibited circular and elliptical morphologies, respectively. Moreover, external water pressure and defect size exerted a significant influence on the expansion of the wet area. Notably, the impact of crack width surpassed that of hole diameter. Encouragingly, the numerical models generated using TOUGH2 for unsaturated concrete demonstrated excellent agreement with laboratory test results concerning the geometry, size, and pattern of the wet area. These findings signified the potential of TOUGH2 numerical simulation as a valuable tool in predicting the lifespan of tunnels.