Using the Submillimeter Array (SMA), we have imaged the 1.3 millimeter continuum emission at the center of the massive star-forming regions NGC 6334 I and I(N). In both regions, the SMA observations resolve the emission into multiple millimeter sources, with most of the sources clustered into areas only 10,000 AU in diameter. Toward NGC 6334 I, we find four compact sources: the two brightest (I-SMA1 and I-SMA2) are associated with previously-known ammonia cores; I-SMA3 is coincident with the peak of the compact HII region (NGC 6334 F); and I-SMA4 is a newly-discovered object. While I-SMA3 exhibits a mixture of free-free and dust emission, the rest of the objects are dust cores. Toward NGC 6334 I(N), seven compact dust cores are found, one of which is associated with a faint centimeter source. With the exception of I-SMA3, none of the millimeter sources have infrared counterparts in Spitzer Space Telescope 3-8 micron images. Using a simple physical model for the dust continuum emission, the estimated mass of interstellar material toward each of these compact objects is in the range of 3 to 66 solar masses. The total mass in the compact objects appears to be similar in I and I(N). The small size of these groups of sources suggest that these objects are proto-Trapezia forming in the centers of clusters of low to intermediate-mass stars.

The combination of a 4 K 22-pole ion trap instrument, FELion, with the widely tunable free electron lasers at the FELIX Laboratory is described in detail. It allows for wide-range infrared vibrational spectroscopy of molecular ions. In this study, the apparatus is used for infrared vibrational predissociation (IR-PD) measurements of the simple alcohol cations of methanol and ethanol as well as their protonated forms. Spectra are taken by tagging the cold molecular ions with He atoms. The infrared spectrum of protonated methanol is recorded for the first time, and the wavelength coverage for all other species is substantially extended. The bands of all spectra are analysed by comparison to ab initio calculation results at different levels of theory. Vibrational bands of different isomers and conformers (rotamers) are discussed and identified in the experimental spectra. Besides the measurement of IR-PD spectra, the method of infrared multiple photon dissociation IR-MPD is applied for some cases. Spectral narrowing due to the cold environment is observed and rotational band contours are simulated. This will help in identifying more complex species using the IR-MPD method in future measurements. Overall the IR-PD spectra reveal more bands than are observed for the IR-MPD spectra. In particular, many new bands are observed in the fingerprint region. Depletion saturation of the finite number of trapped ions is observed for the IR-PD spectra of the ethanol cation and the presence of only one isomeric species is concluded. This special feature of ion trapping spectroscopy may be used in future studies for addressing specific isomers or cleaning the ion cloud from specific isomers or conformers. In addition, the results of this study can be used as a basis to obtain high-resolution infrared vibrational and THz rotational spectra of alcohol ions in order to detect them in space.

Applying a 4 K cryogenic ion trap machine, the linear ion HC₃O⁺ has been investigated by high-resolution ro-vibrational and pure rotational spectroscopy.

The first rovibrational (IR) and rotational (mm-wave) spectra are measured for c-C₃H₂D⁺, a potential detection target in interstellar space.

A novel rotation–vibration double resonance scheme was used to measure the first pure rotational transition frequencies of protonated methanimine (CH ₂ NH ₂ ⁺ ) in a 4 K cryogenic ion trap.