Polar codes, as the coding scheme for the control channel in fifth-generation mobile communication technology (5G), have attracted widespread attention since their proposal. As a mainstream decoding algorithm for polar codes, the successive cancellation list (SCL) decoder usually improves the error correction performance by increasing the list size, but this method suffers from the problems of high decoding complexity. To address this problem, this paper proposes a layered-search bit-flipping (LS-SCLF) decoding algorithm based on SCL decoding. Firstly, a new flip-bit metric is proposed, which derives a formula to approximate the probability of an error occurring in an information bit. This formula introduces a perturbation parameter to improve the calculation accuracy. Secondly, a compromise scheme for determining the perturbation parameter is proposed. The scheme uses Monte Carlo simulation to determine an optimized parameter for the precise positioning of the first erroneous decoded bit under different decoding conditions. Finally, a layered search strategy is adopted to sequentially search the erroneous decoded bits from the low order to high order, which can correct up to multiple bits at the same time. Simulation results show that the proposed algorithm achieves improved error correction performance with a slight increase in decoding complexity compared to the generalized SCL-Flip (GSCLF) decoding algorithm. This algorithm also achieves a good balance between the error correction performance and decoding complexity.