Hydroxylamine nitrate and hydrazine nitrate are dangerous explosives and toxic chemicals. Catalytic decomposition is an efficient way for disposal of these chemicals. In the current work, a Ru/ZSM-5 catalyst has been fabricated and evaluated for the decomposition of hydroxylamine nitrate and hydrazine nitrate in 1.0 mol L−1 HNO3. The hydroxylamine nitrate and hydrazine nitrate can be thoroughly decomposed under 80 °C. And the Ru/ZSM-5 catalyst can be separated from the reaction mixture and reused at least 130 times with stable catalytic performance. Easy operation, less solid waste generation, and a simple catalytic device make the strategy reported here practical, environmentally friendly, and economically attractive.
3 December 2009 in Journal of Radioanalytical and Nuclear Chemistry
Continuous dissolution of spent fuel is indeed one of the key technologies that can significantly improve the efficiency and stability of spent fuel reprocessing. The China Institute of Atomic Energy designed a prototype rotary drum dissolver, and the dissolution behavior of UO2 pellets in the dissolver was calculated using the Discrete Element Method. A kinetic equation was established to model the dissolution behavior, considering variables such as temperature, nitric acid concentration, and stirring intensity. The calculations showed that complete pellet dissolution took about 10 h in the continuous reaction, compared to 6 h in the batch dissolution experiment due to the gradual decrease in nitric acid concentration. A 16 h continuous dissolution experiment confirmed the calculated results, with a deviation of 10.8% between the simulation and experiment in terms of the mass of dissolved pellets. It was also found that it takes approximately 30 h to reach equilibrium in the continuous rotary dissolver, with a nitric acid concentration of 2.8 mol/L and a uranium concentration of 243 g/L at equilibrium.
A mitochondria-targeted long-wavelength fluorescent probe CMP for the detection of HSO3− was reported. It enables real-time detection of HSO3− in cells, zebrafish, CCCP-induced apoptosis and Erastin-induced ferroptosis.
Hydroxylamine nitrate (HAN) and hydrazine nitrate (HN) are commonly found in radioactive waste solutions in nuclear fuel reprocessing, and their efficient removal is essential for waste treatment processes. In this study, six activated carbon carriers were selected to prepare Ru/AC catalysts for the simultaneous catalytic decomposition of HAN and HN, with the aim of exploring the effect of carrier properties on catalytic performance. The catalyst’s activity was evaluated in a batch reaction unit, and its structural properties were characterized using N2 physical adsorption, XRD, SEM, and TEM techniques. The results revealed that the catalyst’s activity was primarily determined by the carrier’s particle size and specific surface area. Additionally, corrosion-induced damage to the pore structure and Ru loss were identified as the main factors responsible for catalyst deactivation. This study highlights the importance of optimizing carrier structure to enhance the activity and stability of Ru/AC catalysts.