In this paper the procedure for catalytical bromination of C60 with elementary bromine with FeBr3 as a catalyst is described. In this procedures only one reaction product - C60 Br24 is obtained. The twenty four bromine atoms are symmetrically distributed over the C60 sphere, which was confirmed by thermogravimetric analysis. The yield of bromine derivative in this reaction is 98%.
The effect of yttria additive on the thermal shock behavior of magnesium aluminate spinel has been investigated. As a starting material we used spinel (MgAl2O4) obtained by the modified glycine nitrate procedure (MGNP). Sintered products were characterized in terms of phase analysis, densities, thermal shock, monitoring the damaged surface area in the refractory specimen during thermal shock and ultrasonic determination of the Dynamic Young modulus of elasticity. It was found that a new phase between yttria and alumina is formed, which improved thermal shock properties of the spinel refractories. Also densification of samples is enhanced by yttria addition.
1 January 2008 in Journal of the European Ceramic Society