Recently, research and development in the field of dye-sensitized solar cells has been actively advanced, as the technology constitutes a potential alternative to silicon-based photovoltaic devices. Modification of the molecular structure of the dye can enhance the adsorption on the TiO₂ surface, improve the light absorption capacity, suppress the charge recombination, increase the electron injection rate, and thereby improve the overall performance of the solar cell. Carbazole and phenothiazine are rigid heterocyclic compounds containing nitrogen as a heteroatom with large π-conjugated skeletons. Phenothiazine differs from carbazole by the presence of sulfur as an additional electron-rich heteroatom. The inclusion of this heteroatom in the structure of the compounds can indeed improve the electron-donating properties, affect the conjugation, and thus affect the optical, electronic, and electrochemical properties of the chromophores as a whole. The difference in planarity when comparing carbazole with phenothiazine can be useful from several points of view. The planar structure of carbazole increases the degree of conjugation and the electron transfer capacity, which can increase the photocurrent of the cell. The nonplanar structure of phenothiazine helps to prevent π-stacking aggregation. This review comprehensively summarizes the progress in the field of synthesis of organic dyes for solar cells with an emphasis on the comparative analysis of two electron-donating moieties, carbazole and phenothiazine. In addition, the review describes in detail the relationship between the structure of the compounds (dyes), their properties, and the performance of solar cells.

In this work, new polymers with a shape memory effect for self-healing coatings based on oligomers with terminal epoxy groups, synthesized from oligotetramethylene oxide dioles of various molecular weights, were developed. For this purpose, a simple and efficient method for the synthesis of oligoetherdiamines with a high yield of the product, close to 94%, was developed. Oligodiol was treated with acrylic acid in the presence of a catalyst, followed by the reaction of the reaction product with aminoethylpiperazine. This synthetic route can easily be upscaled. The resulting products can be used as hardeners for oligomers with terminal epoxy groups synthesized from cyclic and cycloaliphatic diisocyanates. The effect of the molecular weight of newly synthesized diamines on the thermal and mechanical properties of urethane-containing polymers has been studied. Elastomers synthesized from isophorone diisocyanate showed excellent shape fixity and shape recovery ratios of >95% and >94%, respectively.

The effect of polyester oligoethylene adipate molecular weight, diisocyanate structure, and chain extender on the properties of epoxyurethane-based oligomer elastomers was studied in this research. Oligoethylene adipates were obtained via polycondensation of adipic acid and ethylene glycol. Epoxyurethane oligomers were synthesized according to a two-step route with an oligodiisocyanate as an intermediate product. The elastomers with hard urethane hydroxyl blocks were synthesized from oligodiisocyanates. The deformation and strength properties of the elastomers were studied.

A method for the synthesis of oligotetramethylene oxides with terminal amino groups is presented. Its use as a hardener for urethane-containing oligomers has been demonstrated. The diamines were synthesized by a two-stage method based on oligotetramethylene oxide diol. The compounds can be used for the production of non-toxic, biocompatible and biodegradable segmented urethane-containing elastomers. The oligotetramethylene oxide diol with an average molecular mass of 1008 was chosen as a typical precursor component. Its dibromide was formed using a quasi-phosphonium reagent in various solvents. The corresponding amine was obtained by high-pressure amination. The compounds have been identified by ¹H and ¹³C NMR spectroscopy, IR spectroscopy, and elemental analysis.

A number of novel fluorophores have been synthesized containing an electron‐withdrawing pyrimidine core and electron donating N,N ‐dimethylaminophenyl, 4‐(9 H ‐carbazol‐9‐yl)phenyl, phenyl and pyrrol‐1‐yl fragments at positions 2, 4 and 6 of the pyrimidine ring. Thermal, optical and electrochemical properties of these substances have been studied. The structure‐property dependences of substituted pyrimidines have been established.