Two methods—attenuated total reflection Fourier infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS)—have been used to analyze the chemical structure of polytetrafluorethylene (PTFE) thin coatings deposited by pulsed laser (PLD) and pulsed electron beam (PED) ablations. The volume of the analyzed materials is significantly different in these techniques which can be of great importance in the characterization of highly heterogeneous thin films. Optical microscopy, atomic force microscopy (AFM) and scanning electron microscopy (SEM) have been additionally used to examine the coating surface morphology. The studies have shown that in the case of thin polymer coatings deposited by physical methods, the application for chemical structure evaluation of complementary techniques, with different surface sensitivity, together with the use of surface topography imaging, provide unique insight into the film morphology. The results can provide information contributing to an in-depth understanding of the deposition mechanism of polymer coatings.

The presented results make an original contribution to the development of knowledge on the prediction and/or modeling of the abrasive wear properties of polyurethanes. A series of segmented linear polyurethane elastomers (PUR)—In which the hard segments consist of 4,4′-methylene bis(phenylisocyanate) and 1,4-butanodiol, whilst polyether, polycarbonate, or polyester polyols constitute the soft segments—Were synthesized and characterized. The hardness and wear performance as functions of the variable chemical composition of polyurethane elastomers were evaluated in order to define the relationship between studied factors. The microstructure was characterized in detail, including analysis of the hydrogen bonding by Fourier transformed infrared (FT-IR) spectroscopy and the phase structure by X-ray scattering (WAXS) and differential scanning calorimetry (DSC) methods. The presented studies provide the key features of the polymer composition affecting the abrasive resistance as well as attempts to explain the origin of the differences in the polyurethane elastomers’ performance.

This article describes the experimental studies of a preloaded asymmetric multi-bolted connection in the exploitation state. The construction of two stands were introduced: for bolt calibration and for evaluating the bolt forces in a multi-bolted connection. The bolts were tightened in a specific optimal sequence, in three passes, monitoring the force values in the bolts using a calibrated strain gauge measuring system. The studies were conducted for the selected multi-bolted connection on an Instron 8850 testing machine. The measurement data were saved in MATLAB R2018b Simulink. The measurement results were analysed statistically and are presented via charts showing the distributions of the normalised values of the bolt forces as a function of the linearly increasing and decreasing exploitation loads. We show that the forces in individual bolts, after unloading the multi-bolted connection, change in relation to the initial values of their preload.

The aim of this paper is to extend knowledge on biobased poly(butylene furanoate)–block–poly (ethylene oxide) (PBF-b-PEO) copolymers’ performance by studying the effect of the PEO segment’s molecular weight on the microstructure and materials behavior. As crystallization ability of PEO depends on its molecular weight, the idea was to use two PEO segment lengths, expecting that the longer one would be able to crystallize affecting the phase separation in copolymers, thus affecting their mechanical performance, including elasticity. Two series of PBF-block-PEOs with the PEO segments of 1000 and 2000 g/mol and different PBF/PEO segment ratios were synthesized by polycondensation in melt, injection molded to confirm their processability, and subjected to characterization by NMR, FTIR, DSC, DMTA, WAXS, TGA, and mechanical parameters. Indeed, the PEO2000 segment not only supported the crystallization of the PBF segments in copolymers, but at contents at least 50 wt % is getting crystallizable in the low temperature range, which results in the microstructure development and affects the mechanical properties. While the improvement in the phase separation slightly reduces the copolymers’ ability to deformation, it is beneficial for the elastic recovery of the materials. The investigations were performed on the injection molded samples reflecting the macroscopic properties of the bulk materials.

Poly(ethylene-co-vinyl acetate) (EVA) films were deposited for the first time using physical methods. The chemical structure of the films obtained using two techniques, pulsed electron beam deposition (PED) and pulsed laser deposition (PLD), was studied by attenuated total reflection Fourier infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS). Whilst significant molecular degradation of the EVA films was observed for the PLD method, the original macromolecular structure was only partially degraded when the PED technique was used, emphasizing the superiority of the PED method over PLD for structurally complex polymers such as EVA. Optical and scanning electron microscopic observations revealed compact and smooth EVA films deposited by pulsed electron beam ablation as opposed to heterogeneous films with many different sized particulates obtained by PLD.

Manufacturers of adhesives for industrial use determine the strength of adhesive joints during shear tests. Most often, components made of the same material are joined. In contrast, the roughness of the surfaces to be joined results from the use of a specific surface treatment technology. In adhesive manufacturers’ recommendations for metal-to-metal joints, surface technologies can be found without specifying numerical requirements for roughness. Modern techniques for shaping the geometric accuracy of components allow the formation of determined irregularities on the surface, which are characterised by their height and mutual distribution. Furthermore, regular irregularities can be obtained by using the appropriate tool and technological machining parameters. In this way, surfaces with similar load-bearing capacity, core volume, texture or expected hydrophobic properties can be produced by various methods. However, a basic prerequisite is the careful definition of the numerical requirements, both for the basic roughness indices and those of a complementary nature. As a rule, the strength of the adhesive joint is also lower than the strength of the adhesive itself. The strength of an adhesive joint depends on the ‘mechanical anchorage’ of the adhesive and the adhesion phenomenon on the surface. The research assumes that it is possible to induce an interaction between the geometric state of the surface and the properties of the adhesive, so as to guarantee the maximum strength of the adhesive joint. To verify this, a series of experimental tests were developed and carried out for two different adhesives characterised by different viscosities and offered bond strength. Based on the tests carried out, recommendations were made to the designers of adhesive joints, where, in addition to the height of the surface irregularities, the properties related to fluid retention and the shape of the irregularities in the valleys should be determined.