The results of studies on the influence of periodically stacked nanolayer inclusions, introduced into the face-centered cubic (f.c.c.) hard sphere crystal, on Poisson’s ratio of the obtained nanocomposite system are presented. The monolayers are orthogonal to the $\left[001\right]$ -direction. They are formed by hard spheres with diameter different from the spheres forming the matrix of the system. The Monte Carlo computer simulations show that in such a case the symmetry of the system changes from the cubic to tetragonal one. When the diameter of the inclusion spheres increases at certain range, a decrease of the negative Poisson’s ratio in the $\left[101\right]\left[\overline{1}01\right]$ -directions is observed, i.e., the system enhances its partial auxeticity. The dependence of the maximal, average, and negative parts of the minimal Poisson’s ratio on the direction of the applied load are shown in a form of surfaces in spherical coordinates, plotted for selected values of nanolayer particle diameters. The most negative value of the Poisson’s ratio found among all studied systems was $-0.11$ (at pressure $p^{*}=100$ , which is about ten times higher than the melting pressure) what is almost twice more negative than in the f.c.c. crystal of identical hard spheres. The observed effect weakens along with the decrease of pressure and becomes hardly noticeable near melting. This study indicates that modifying only the size of the inclusion particles one can change Poisson’s ratio of nanocomposites at high pressures.

Tailoring the materials for a given task by modifying their elastic properties is attractive to material scientists. However, recent studies of purely geometrical atomic models with structural modifications showed that designing a particular change to achieve the desired elastic properties is complex. This work concerns the impact of nanochannel inclusions in fcc hard sphere crystal on its elastic properties, especially auxetic ones. The models containing six nanochannel arrays of spheres of another diameter, oriented along the [110]-direction and its symmetric equivalents, have been studied by Monte Carlo simulations in the isothermal-isobaric $\left(NpT\right)$ ensemble using the Parinello-Rahman approach. The inclusions have been designed such that they do not affect the cubic symmetry of the crystal. The elastic properties of three different models containing inclusions of various sizes are investigated under four thermodynamic conditions. We find that six nanochannels filled with hard spheres of larger diameter increase system stiffness compared with the fcc crystal without nanoinclusions. The current finding contrasts the recently reported results [J.W. Narojczyk et al. Phys. Status Solidi B 259, 2200464 (2022)], where the fcc hard sphere crystal with four nanochannels shows reduced stiffness compared to the system without nanoinclusions. Moreover, the six nanochannel models preserve auxetic properties in contrast to the fcc hard sphere crystal with four nanochannel arrays, which loses auxeticity.

The paper is dedicated to the life prolongation of the tools designed for deep-hole drilling. Among available methods, an ion implantation process was used to improve the durability of tungsten carbide (WC)-Co guide pads. Nitrogen fluencies of 3 × 10¹⁷ cm⁻², 4 × 10¹⁷ cm⁻² and 5 × 10¹⁷ cm⁻² were applied, and scanning electron microscope (SEM) observations, energy dispersive spectroscopy (EDS) analyses, X-ray photoelectron spectroscopy (XPS) and Secondary Ion Mass Spectrometry (SIMS) measurements were performed for both nonimplanted and implanted tools. The durability tests of nonimplanted and the modified tools were performed in industrial conditions. The durability of implanted guide pads was above 2.5 times greater than nonimplanted ones in the best case, presumably due to the presence of a carbon-rich layer and extremely hard tungsten nitrides. The achieved effect may be attributed to the dissociation of tungsten carbide phase and to the lubrication effect. The latter was due to the presence of pure carbon layer with a thickness of a few dozen nanometers. Notably, this layer was formed at a temperature of 200 °C, much smaller than in previously reported research, which makes the findings even more valuable from economic and environmental perspectives.

In this work we present results of Monte Carlo simulations of the elastic properties of Yukawa crystals with the polydispersity of size of particles. The results of our studies reveal an enhancement of negative Poisson's ratio (further referred to as auxeticity) due to size polydispersity in the system. We introduce a measure of auxeticity to estimate quantitatively an enhancement of auxetic properties which can be used to assess those changes in various systems.