Nanotechnology is playing a pivotal role in improving quality of life due to its versatile applications in many areas of research. In this regard, nanoparticles have gained significant importance. Zinc oxide nanoparticles (ZnO NPs) amongst other nanoparticles are being used in producing nanocomposites. Methods like solvent casting, solution casting, solvent volatilization, twin-screw extrusion, melt compounding and extrusion blow molding have been applied to produce ZnO NPs based (bio)polymer composites. These composites are of great interest in the research area of food packaging materials due to their improved multifunctional characteristics like their mechanical, barrier and antimicrobial properties. This paper gives an overview of the main methods to synthesize ZnO NPs, methods to incorporate ZnO NPs in (bio)polymers, and finally, the gas barrier and mechanical properties of the nanocomposites. As a conclusion, a maximum decline in oxygen, carbon dioxide and water vapor permeability was reported as 66%, 17% and 38% respectively, while tensile strength and young’s modulus were observed to increase by 32% and 57% respectively, for different (bio)polymer/ZnO nanocomposites.
This paper presents the formulation, inkjet printing, and vacuum forming of a conductive and stretchable polymer, poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), ink on a stretchable and transparent thermoplastic polyurethane (TPU) substrate. The formulation of the conductive and stretchable ink is achieved by combining PEDOT:PSS with additional solvents, to achieve the right inkjet properties for drop-on-demand (DoD) inkjet printing. A conductive pattern can be printed from the 21 µm orifice on a flexible and stretchable TPU substrate, with a linewidth down to 44 µm. The properties of the printed pattern, in terms of sheet resistance, morphology, transparency, impact of weather conditions, and stretching are investigated and show sheet resistances up to 45 Ohm/sq and transparencies as high as 95%, which is comparable to indium tin oxide (ITO). Moreover, in contrast to ITO, one-time stretching up to 40% can be achieved, increasing the sheet resistance up to 214 Ohm/sq only, showing the great potential of this ink for one-time stretching. Finally, as a proof of this one-time stretching, the printed samples are vacuum formed around a 3D object, still showing sufficient conductivity to be applied as a capacitive touch sensor.
Centrifugal fiber spinning has recently emerged as a highly promising alternative technique for the production of nonwoven, ultrafine fiber mats. Due to its high production rate, it could provide a more technologically relevant fiber spinning technique than electrospinning. In this contribution, we examine the influence of polymer concentration and nozzle material on the centrifugal spinning process and the fiber morphology. We find that increasing the polymer concentration transforms the process from a beaded-fiber regime to a continuous-fiber regime. Furthermore, we find that not only fiber diameter is strongly concentration-dependent, but also the nozzle material plays a significant role, especially in the continuous-fiber regime. This was evaluated by the use of a polytetrafluoroethylene (PTFE) and an aluminum nozzle. We discuss the influence of polymer concentration on fiber morphology and show that the choice of nozzle material has a significant influence on the fiber diameter.
The healthcare system is moving away from traditional hospital-centric models towards a more personalised, patient-centric approach driven by the concept called ‘lab on wearables’. The nucleus of this concept is grounded on the translation of biological signals into actionable healing information with the help of soft, conformable and biocompatible sensors. This soft flexible electronic platform development is more leaning towards unconventional electronics fabrication routes like printed electronics over clean room based micro-electronics manufacturing. Printed electronics can harness the potential of stretchable foils, bio-derived functional materials and organic electronics, enabling the development of biodegradable and bioresorbable wound monitoring systems that are conformable with the skin. The review explores the potential of sustainable and biocompatible printed electronics in transducing wound biomarkers into actionable healing insights, enabling timely interventions. This work also provides a roadmap for printed electronics-based wound monitoring and on-demand treatment solutions, offering a glimpse into the future promises of the technology.
Stretchable electronics promise to naturalize the way that we are surrounded by and interact with our devices. Sensors that can stretch and bend furthermore have become increasingly relevant as the technology behind them matures rapidly from lab-based workflows to industrially applicable production principles. Regardless of the specific materials used, creating stretchable conductors involves either the implementation of strain reliefs through insightful geometric patterning, the dispersion of stiff conductive filler in an elastomeric matrix, or the employment of intrinsically stretchable conductive materials. These basic principles however have spawned a myriad of materials systems wherein future application engineers need to find their way. This paper reports a literature study on the spectrum of different approaches towards stretchable electronics, discusses standardization of characteristic tests together with their reports and estimates matureness for industry. Patterned copper foils that are embedded in elastomeric sheets, which are closest to conventional electronic circuits processing, make up one end of the spectrum. Furthest from industry are the more recent circuits based on intrinsically stretchable liquid metals. These show extremely promising results, however, as a technology, liquid metal is not mature enough to be adapted. Printing makes up the transition between both ends, and is also well established on an industrial level, but traditionally not linked to creating electronics. Even though a certain level of maturity was found amongst the approaches that are reviewed herein, industrial adaptation for consumer electronics remains unpredictable without a designated break-through commercial application.