Cerium-doped zinc cobaltite spinel thin films, , were synthesized via spray pyrolysis, and their structural, morphological, optical, and electrical properties were analyzed. X-ray diffraction (XRD) confirmed a cubic spinel structure with a predominant (311) orientation across all compositions. Raman spectroscopy further verified this phase, revealing four active vibrational modes at 180 cm−1, 470 cm−1, 515 cm−1, and 682 cm−1. Scanning electron microscopy (SEM) indicated a uniform grain distribution, while energy-dispersive X-ray spectroscopy (EDS) confirmed the presence of Ce, Zn, Co, and O. Optical measurements revealed two distinct bandgaps, decreasing from 2.32 eV to 2.20 eV for the lower-energy transition and from 3.38 eV to 3.18 eV for the higher-energy transition. Hall effect measurements confirmed p-type conductivity in all films. Electrical analysis showed a reduction in resistivity, from 280.3 Ω·cm to 15.4 Ω·cm, along with an increase in carrier concentration from 1.15 × 1016 cm−3 to 8.15 × 1017 cm−3 with higher Ce content. These results demonstrate that spray pyrolysis is a cost-effective and scalable method for producing Ce-doped ZnCo2O4 thin films with tunable properties, making them suitable for electronic and optoelectronic applications.
Assessing tourism sustainability has become of paramount importance to researchers and policymakers in regard to better protecting tourism destinations, particularly with the continued increase in the number of tourists and visitors who alter the natural components of the environment and degrade ecosystems. The use of geographic data is of great importance, as it can serve as a dashboard for monitoring and controlling the sustainability of tourist areas. Due to their diversity and abundance in the city of Tangier, these tools are available and easy to use. The medina of Tangier is used as a calculation example, a method that will also be applicable to other areas of the metropolitan city and to other cities as well. Based on the annual meeting of the different component of society involved in the Medina of Tangier, the data are extracted and integrated into the proposed model through a plugin interface. Therefore, the use of geographic data is of great importance, especially in environmental monitoring and land management, due to its ease of use and availability. However, calculating composite sustainability indices involves several steps and requires a basic understanding of existing models. This article describes the development and design of a plugin package in QGIS that serves as an easy-to-use tool to automatically process and calculate economic, environmental and social indices and the overall tourism sustainability index. These plugins were built in Python and designed as plugins for the QGIS software version 3.22.
The evaluation of tourism sustainability has become of paramount importance for researchers and decision-makers to better protect tourist destinations, especially with the continuous increase in the number of tourists and visitors that alter the natural components of the environment and degrade ecosystems. Therefore, the use of geographical data is of great significance, particularly in environmental monitoring and land management, due to its ease of use and availability. However, calculating composite indices for sustainability involves several steps and requires a basic understanding of existing models. This article describes the development and design of a package of plugins in QGIS that serves as an easy-to-use tool for processing and automatically calculating economic, environmental, social indices, and the overall index of tourist sustainability. These plugins have been built in Python and designed as QGIS software plugins.