Reconstructing changes in deep/bottom-water redox conditions are critical for understanding the role of the deep ocean in global carbon and metals cycling; nevertheless, the quantitative relationships between redox proxies and abyssal dissolved oxygen are poorly investigated. In this work, we studied the rock magnetic properties of surficial sediments in the western Pacific to investigate their relationship with regional redox conditions. Our results reveal a consistent sedimentary magnetic mineral assemblage in the western Pacific, dominated by pseudo-single-domain magnetite (Fe3O4), while the ratio of detrital and biogenic magnetite particles in different sites varies substantially. Detailed analyses identified two major magnetic-coercivity components, with modal coercivity values of 13.1 ± 1.6 mT and 54.7 ± 5.3 mT, respectively. All the magnetic parameters we measured, including both concentration-dependent and grainsize-dependent parameters, and the magnetic coercivities, are generally correlated to sedimentary redox conditions; however, the coercivities obtained by mathematical unmixing exhibit a stronger linkage, explaining about a quarter of variance of redox changes. Our findings confirm the potential of magnetic properties for tracing abyssal redox changes in the western Pacific, while the observed magnetic-redox relationships are complex and need further investigation.
The stability of contemporary ice shelves is under threat due to global warming, and the geological records in the Ross Sea offer such an opportunity to test the linkage between them. However, the absence of calcareous microfossils in the sediments of the Ross Sea results in uncertainties in establishing a precise chronology for studies. Hence, three sediment cores were collected and studied in terms of radiocarbon dating, magnetic susceptibility, and sediment grain size to reconstruct the environmental processes in the Ross Sea since the last glacial period. The main results are as follows: (1) two grain-size components were identified for the studied cores, which can be correlated to ice-shelf and sea-ice transport, respectively; (2) due to old-carbon contamination and an inconsistent carbon reservoir, the radiocarbon dates were generally underestimated, and as an alternative, changes in magnetic susceptibility of the studied cores can be tuned to the ice-core records to establish a reliable age–depth model and; (3) integrating sediment grain-size changes and comparisons with other paleoenvironmental proxies in the Antarctic, a process from a sub-ice sheet in the last glacial period to a sub-ice shelf in the glacial maximum, and, finally, to a glaciomarine state since the last deglacial period was identified in the western Ross Sea. Integrating these findings, the warming processes in the Antarctic were highlighted in the retreat processes of the Ross Ice Shelf in the past.