Group VIB transition metal dichalcogenides (TMDs) have been successfully demonstrated as saturable absorbers (SAs) for pulsed fiber lasers. For the group comprising IVB TMDs, applications in this field remain unexplored. In this work, ZrS₂-based SA is prepared by depositing a ZrS₂ nanostructured film onto the side surface of a D-shaped fiber. The nonlinear optical properties of the prepared SA are investigated, which had a modulation depth of 3.3% and a saturable intensity of 13.26 MW/cm². In a pump power range of 144–479 mW, the Er-doped fiber (EDF) laser with ZrS₂ can operate in the dual-wavelength Q-switching state. The pulse duration declined from 10.0 μs down to 2.3 μs. The single pulse energy reached 53.0 nJ. The usage of ZrS₂ as a SA for pulse generation in fiber lasers is presented for the first time. Compared to the experimental results of dual-wavelength Q-switched fiber lasers with two-dimensional (2D) materials, our laser performance was better. Our work indicates that the group comprising IVB TMD ZrS₂ has bright prospects for nonlinear optical applications.

The two-dimensional (2D) layered material MoS2 has attracted numerous attentions for electronics and optoelectronics applications. In this work, a novel ty

Molybdenum carbide (Mo₂C) is a two-dimensional (2D) MXene material which makes it a promising photoelectric material. In this study, reflective type MXene Mo₂C thin films were coated on a silver mirror by a magnetron sputtering method and were subsequently used in a passively Q-switched solid-state pulsed laser generator at the central wavelengths of 1.06 and 1.34 μm, respectively. The fabricated thin films of reflective type MXene Mo₂C exhibited large modulation depth of 6.86% and 5.38% at the central wavelengths of 1064 and 1342 nm, respectively. By inserting the Mo₂C saturable absorbers (SAs) into V-shaped Nd:YAG laser, short pulses were generated having a pulse duration, pulse energy, and average output power of 254 ns, 2.96 μJ, and 275 mW, respectively, at a wavelength of 1.06 μm. Similarly, shorter laser pulses were obtained in Nd:YVO₄ laser at 1.34 μm. Our results illustrated potential of the 2D MXene Mo₂C films for laser applications.