Efficient production of nuclear isomers is critical for pioneering applications, like nuclear clocks, nuclear batteries, clean nuclear energy, and nuclear $\gamma$-ray lasers. However, due to small production cross sections and quick decays, it is extremely difficult to acquire a significant amount of isomers with short lifetimes via traditional accelerators or reactors because of low beam intensity. Here, for the first time, we experimentally present femtosecond pumping of nuclear isomeric states by the Coulomb excitation of ions with the quivering electrons induced by laser fields. Nuclei populated on the third excited state of ${}^{83}\mathrm{Kr}$ are generated with a peak efficiency of $2.34\times {10}^{15}\text{particles}/\mathrm{s}$ from a tabletop hundred-TW laser system. It can be explained by the Coulomb excitation of ions with the quivering electrons during the interaction between laser pulses and clusters at nearly solid densities. This efficient and universal production method can be widely used for pumping isotopes with excited state lifetimes down to picoseconds, and could be a benefit for fields like nuclear transition mechanisms and nuclear $\gamma$-ray lasers.

Fermi acceleration is believed to be the primary mechanism to produce high-energy charged particles in the Universe, where charged particles gain energy successively from multiple reflections. Here, we present the direct laboratory experimental evidence of ion energization from single reflection off a supercritical collisionless shock, an essential component of Fermi acceleration, in a laser-produced magnetized plasma. A quasi-monoenergetic ion beam with two to four times the shock velocity was observed, which is consistent with the fast ion component observed in the Earth’s bow shock. Our simulations reproduced the energy gain and showed that ions were accelerated mainly by the motional electric field during reflection. The results identify shock drift acceleration as the dominant ion energization mechanism, which is consistent with satellite observation in the Earth’s bow shock. Our observations pave the way for laboratory investigations of the cosmic accelerators, also be beneficial to laser fusion and laser-driven ion accelerator.