Thermodynamic uncertainty relations (TURs) place strict bounds on the fluctuations of thermodynamic quantities in terms of the associated entropy production. In this Letter, we identify the tightest (and saturable) matrix-valued TUR that can be derived from the exchange fluctuation theorems describing the statistics of heat and particle flow between multiple systems of arbitrary dimensions. Our result holds for both quantum and classical systems, undergoing general finite-time nonstationary processes. Moreover, it provides bounds not only for the variances, but also for the correlations between thermodynamic quantities. To demonstrate the relevance of TURs to the design of nanoscale machines, we consider the operation of a 2-qubit swap engine undergoing an Otto cycle and show how our results can be used to place strict bounds on the correlations between heat and work.
Autonomous engines operating at the nanoscale can be prone to deleterious fluctuations in the heat and particle currents. Thermodynamic uncertainty relations (TURs) express a fundamental lower bound which translates a trade-off relation between precision and entropy production. Importantly, recent studies have shown that they can be violated in the quantum regime, thus motivating the search for analogous quantum counterparts. In this paper, we show that the geometry of quantum nonequilibrium steady states alone directly implies the existence of TUR, but with a looser bound, which is not violated by the above recent findings. The geometrical nature of this result makes it extremely general, establishing a fundamental limit for the thermodynamics of precision. Our proof is based on the McLennan-Zubarev ensemble, which provides an exact description of nonequilibrium steady states. We first prove that the entropy production of this ensemble can be expressed as a quantum relative entropy. The TURs are then shown to be a direct consequence of the Cramer-Rao bound, a fundamental result from parameter estimation theory. By combining techniques from many-body physics and information sciences, our approach also helps to shed light on the delicate relationship between quantum effects and current fluctuations in autonomous machines, where new general bound on the power output are found and discussed.
The precise measurement of low temperatures is a challenging, important, and fundamental task for quantum science. In particular, in situ thermometry is highly desirable for cold atomic systems due to their potential for quantum simulation. Here, we demonstrate that the temperature of a noninteracting Fermi gas can be accurately inferred from the nonequilibrium dynamics of impurities immersed within it, using an interferometric protocol and established experimental methods. Adopting tools from the theory of quantum parameter estimation, we show that our proposed scheme achieves optimal precision in the relevant temperature regime for degenerate Fermi gases in current experiments. We also discover an intriguing trade-off between measurement time and thermometric precision that is controlled by the impurity-gas coupling, with weak coupling leading to the greatest sensitivities. This is explained as a consequence of the slow decoherence associated with the onset of the Anderson orthogonality catastrophe, which dominates the gas dynamics following its local interaction with the immersed impurity.
Thermodynamic uncertainty relations express a trade-off between precision, defined as the noise-to-signal ratio of a generic current, and the amount of associated entropy production. These results have deep consequences for autonomous heat engines operating at steady state, imposing an upper bound for their efficiency in terms of the power yield and its fluctuations. In the present Letter we analyze a different class of heat engines, namely, those which are operating in the periodic slow-driving regime. We show that an alternative TUR is satisfied, which is less restrictive than that of steady-state engines: it allows for engines that produce finite power, with small power fluctuations, to operate close to reversibility. The bound further incorporates the effect of quantum fluctuations, which reduces engine efficiency relative to the average power and reliability. We finally illustrate our findings in the experimentally relevant model of a single-ion heat engine.
We explore the connection between two recently introduced notions of non-Markovian quantum dynamics and the validity of the so-called quantum regression theorem. While non-Markovianity of a quantum dynamics has been defined looking at the behavior in time of the statistical operator, which determines the evolution of mean values, the quantum regression theorem makes statements about the behavior of system correlation functions of order two and higher. The comparison relies on an estimate of the validity of the quantum regression hypothesis, which can be obtained exactly evaluating two-point correlation functions. To this aim we consider a qubit undergoing dephasing due to interaction with a bosonic bath, comparing the exact evaluation of the non-Markovianity measures with the violation of the quantum regression theorem for a class of spectral densities. We further study a photonic dephasing model, recently exploited for the experimental measurement of non-Markovianity. It appears that while a non-Markovian dynamics according to either definition brings with itself violation of the regression hypothesis, even Markovian dynamics can lead to a failure of the regression relation.
We identify sufficient conditions on the structure of the interaction Hamiltonian between a two-level quantum system and a thermal bath that, without any external drive or coherent measurement, guarantee the generation of steady-state coherences (SSC). The SSC obtained this way, remarkably, turn out to be independent of the initial state of the system, which could therefore be taken as initially incoherent. We characterize in detail this phenomenon, first analytically in the weak coupling regime for two paradigmatic models, and then numerically in more complex systems without any assumption on the coupling strength. In all of these cases, we find that SSC become increasingly significant as the bath is cooled down. These results can be directly verified in many experimental platforms.