In regions characterized by the challenging combination of brine corrosion in the salt lakes and river sand with alkali silica reaction (ASR) activity in areas of the Northwest, high-performance concrete (HPC) formulated with high-volume composite mineral admixtures as ASR suppression measures has been preferred for civil engineering structures in the region. This study investigates the splitting tensile strength, corrosion products, microscopic structure characteristics, and mesoscopic mechanical mechanisms of splitting failure of such HPC under 10-year corrosion from salt lake brine. The relationship between mechanical properties and corrosion damage, as well as the characteristics of internal crack propagation paths and failure mechanisms of HPC under splitting load, are explored. The findings reveal that as the alkali content within HPC rises, corrosion damage intensifies, resulting in a reduction in splitting tensile strength. Moreover, a linear association between mechanical properties and corrosion damage is observed. Microscopic structural analysis and numerical simulation of the splitting failure process of HPC elucidate that while the substantial presence of mineral admixtures effectively suppresses the ASR risk associated with alkali-reactive aggregates in concrete, uneven ASR gel products persist. These discontinuous micro-fine interface cracks induced by the gel products and the cracks induced by the gel products around the selective alkali-active aggregate particles distributed in the local area are the initiation sources of mortar cracks in HPC splitting failure. In terms of the overall failure state observed during the concrete splitting process, mortar cracks manifest two distinct extension paths: along the coarse aggregate interface and directly through the aggregates themselves. Notably, a greater proportion of coarse aggregates are directly penetrated by mortar cracks, as opposed to the number of interface failures bypassing coarse aggregates. More importantly, the above work establishes a theoretical reference in three dimensions: macroscopic, mesoscopic, and microscopic, for studying concrete corrosion damage in complex environments such as salt lake brine corrosion and ASR inhibition.
The natural environment in the high-altitude regions of Northwest China is extremely harsh, characterized by numerous salt lakes. The high concentrations of chloride salts, sulfates, and alkali metal ions in these areas can induce alkali–silica reactions (ASRs) in concrete. These reactions generate harmful gel within the concrete, causing expansion and cracking, which significantly impacts the durability of concrete structures. This study investigates the evolution of the mechanical properties in high-performance concrete (HPC) under long-term ASR by incorporating different admixtures and varying the equivalent alkali content. A three-dimensional random aggregate mesoscopic model was used to simulate static compression tests under various operational conditions. Non-destructive testing methods were utilized to determine the expansion rate, internal, and surface damage variables of the concrete. The experimental results indicate that the 10-year expansion rate differs from the 1-year rate by approximately 1%, and under long-term ASR mitigation measures, the internal damage in the HPC is minimal, though the surface damage is more severe. As the equivalent alkali content increases, the compressive strength of the concrete cubes decreases, initially rising before falling by 5–15% over time. The HPC with only air-entraining agent added exhibited better mechanical performance than the HPC with both air-entraining and corrosion inhibitors added, with the poorest performance observed in the HPC with only a corrosion inhibitor. A relationship was established between the surface and internal damage variables, with the surface damage initially increasing rapidly before stabilizing as the internal damage rose. Numerical simulations effectively describe the damage behavior of HPC under static uniaxial compression. Comparisons with actual failure morphologies revealed that, in the cube compression tests, crack propagation directly penetrated both coarse and fine aggregates rather than circumventing them. The simulations closely matched the experimental outcomes, demonstrating their accuracy in modeling experiments. This study discusses the compressive mechanical properties of concrete under prolonged ASR through a combination of experimental and simulation approaches. It also delves into the impact of surface damage on the overall mechanical performance and failure modes of concrete. The findings provide experimental and simulation support for the concrete structures in regions with high alkali contents.
The salt lake and saline–alkali soil regions of high plateaus are characterized by widespread Alkali–silica reactive (ASR) aggregates, which severely threaten the durability of constructed infrastructure, including railways, highways, and buildings. The research systematically investigates the uniaxial compressive mechanical behavior and stress–strain constitutive relationship of high-performance concrete (HPC) with ASR mitigation measures (performance grades C40, C45, C50, and C60) after ten years of immersion in a standard alkali solution. A corresponding three-dimensional random aggregate mesoscopic concrete model was developed, and mesomechanical numerical simulations were performed to explore the failure process, failure patterns, and underlying mesoscopic damage mechanisms of the specimens. Results show that While the uniaxial compressive strength and elastic modulus of HPC show an expected increase with the concrete strength grade following long-term alkali exposure, both properties demonstrate a clear decline as the equivalent alkali content rises. Comparing and analyzing the C50 specimens of different admixtures, it was found that the air-entraining agent provided the most effective ASR suppression and obtained the highest uniaxial compressive strength compared with the rust inhibitor. By normalizing the stress–strain curves, the long-term constitutive behavior of HPC under alkali corrosion was summarized. Furthermore, mesoscopic model visualizations indicate that cracks initially appear in the mortar and gradually propagate inward during loading, leading to compressive failure characterized by diagonal cracks. Tracking the mesoscopic damage patterns within the specimens demonstrates that microcracks originate in the mortar and progressively extend through aggregates, revealing the underlying micro-damage mechanism. By studying the SEM-EDS images, it is found that HPC with a specific mix ratio designed in this paper can effectively inhibit the ASR effect, and it still has good corrosion resistance in long-term alkali immersion.