Recently, the development of high-performance non-platinum electrocatalysts for fuel cell applications has been gaining attention. Palladium-based nanoalloys are considered as promising candidates to substitute platinum catalysts for cathodic and anodic reactions in fuel cells. Here, we develop a facile route to synthesize dendritic palladium–copper–cobalt trimetallic nanoalloys as robust multifunctional electrocatalysts for oxygen reduction and formic acid oxidation. To the best of our knowledge, the mass activities of the dendritic Pd₅₉Cu₃₀Co₁₁ nanoalloy toward oxygen reduction and formic acid oxidation are higher than those previously reported for non-platinum metal nanocatalysts. The Pd₅₉Cu₃₀Co₁₁ nanoalloys also exhibit superior durability for oxygen reduction and formic acid oxidation as well as good antimethanol/ethanol interference ability compared to a commercial platinum/carbon catalyst. The high performance of the dendritic Pd₅₉Cu₃₀Co₁₁ nanoalloys is attributed to a combination of effects, including defects, a synergistic effect, change of d-band center of palladium, and surface strain.

Synergetic effects between Pt and a cheap metal, downshift of the d-band center of Pt and the shape can boost the catalytic performance of Pt-based nanocrystals. Therefore, tailoring the shape and composition within the nanoscale is the key to designing a robust electrocatalyst in electrochemical energy conversion. Here, Cu-rich PtCu octahedral alloys achieved by a composition-driven shape evolution route have been used as outstanding bifunctional electrocatalysts for both methanol oxidation (MOR) and oxygen reduction reaction (ORR) in an acid medium. When benchmarked against commercial Pt black or Pt/C, for MOR, the specific activity/mass activity on Pt_34.5Cu_65.5 octahedra is 4.74/7.53 times higher than that on commercial Pt black; for ORR, the specific activity/mass activity on Pt_34.5Cu_65.5 octahedra is 7.7/4.2 times higher than that on commercial Pt/C. After a current–time test for 3600 s, the remaining mass activity on Pt_34.5Cu_65.5 octahedra is 35.5 times higher than that on commercial Pt black for MOR. After undergoing 5000 cycles for ORR, the remaining mass activity on Pt_34.5Cu_65.5 octahedra is 4.2 times higher than that on commercial Pt/C.

Recently, engineering high performance Pd-based nanocatalysts for alkaline ethanol fuel cells has attracted wide attention. Here, we report a one-pot synthesis of low-palladium ternary palladium–copper–cobalt (PdCuCo) alloy nanowires (NWs) with a diameter of ∼4.0 nm to improve the mass activity (MA) of ethanol electrooxidation in alkaline medium. The MA (7.45 A mg⁻¹) of the Pd₃₁Cu₆₁Co₈ NWs is 8.5-fold and 12.4-fold that of commercial Pd black and Pd/C, respectively. The reaction mechanism of the EOR and the reasons for the activity enhancement on Pd₃₁Cu₆₁Co₈ NWs are elucidated based on the results of in situ Fourier transform infrared spectroscopy and structure characterization. Besides the electronic effect and surface defect sites, the coexistence of surface Cu and Co that have high capacities to activate water to produce reactive oxygen species is another key factor. This study shows an example of how to design low-palladium ternary PdCuCo NWs as improved anode electrocatalysts for alkaline direct ethanol fuel cells with high mass activity.

Photocatalytic technology has been recently conducted to remove microbial contamination due to its unique features of nontoxic by-products, low cost, negligible microbial resistance and broad-spectrum elimination capacity. Herein, a novel two dimensional (2D) g-C₃N₄/Bi(OH)₃ (CNB) heterojunction was fabricated byincorporating Bi(OH)₃ (BOH) nanoparticles with g-C₃N₄ (CN) nanosheets. This CNB heterojunction exhibited high photocatalytic antibacterial efficiency (99.3%) against Escherichia coli (E. coli) under visible light irradiation, which was 4.3 and 3.4 times that of BOH (23.0%) and CN (28.0%), respectively. The increase in specific surface area, ultra-thin layered structure, construction of a heterojunction and enhancement of visible light absorption were conducive to facilitating the separation and transfer of photoinduced charge carriers. Live/dead cell staining, sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) assays and scanning electron microscopy (SEM) have been implemented to investigate the damage to the cell membrane and the leakage of the intracellular protein in the photocatalytic antibacterial process. The e⁻, h⁺ and O₂^•− were the active species involved in this process. This study proposed an appropriate photocatalyst for efficient treatment of bacterial contamination.