Proton exchange membrane fuel cells (PEMFCs) have the potential to tackle major challenges associated with fossil fuel-sourced energy consumption. Nafion, a perfluorosulfonic acid (PFSA) membrane that has high proton conductivity and good chemical stability, is a standard proton exchange membrane (PEM) used in PEMFCs. However, PEM degradation is one of the significant issues in the long-term operation of PEMFCs. Membrane degradation can lead to a decrease in the performance and the lifespan of PEMFCs. The membrane can degrade through chemical, mechanical, and thermal pathways. This paper reviews the different causes of all three routes of PFSA degradation, underlying mechanisms, their effects, and mitigation strategies. A better understanding of different degradation pathways and mechanisms is valuable in producing robust fuel cell membranes. Hence, the progress in membrane fabrication for PEMFC application is also explored and summarized.

This review highlights our 3-pronged approach to improving ionomer behavior at interfaces and addressing proton conduction limitations in proton exchange membrane fuel cells (PEMFCs), an eco-friendly solution for powering vehicles and devices.